Highly Luminescent Self-Organized Sub-2-nm EuOF Nanowires

被引：112

作者：

Du, Ya-Ping ^{[1
,2
]}

Zhang, Ya-Wen ^{[1
,2
]}

Yan, Zheng-Guang ^{[3
]}

Sun, Ling-Dong ^{[1
,2
]}

Yan, Chun-Hua ^{[1
,2
]}

机构：

[1] Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

[2] Peking Univ, PKU HKU Joint Lab Rare Earth Mat & Bioinorgan Che, Beijing 100871, Peoples R China

[3] Beijing Univ Technol, Beijing 100022, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 45期

关键词：

MONODISPERSE NANOCRYSTALS; AU NANOWIRES; NANOPARTICLES; PRECURSORS; COMPLEXES; EMISSION; SIZE;

D O I：

10.1021/ja9080088

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monodisperse sub-2-nm EuOF nanowires were obtained by manipulating the fluorophilicity between crystalline seeds and capping surfactant molecules during the thermolysis of Eu(CF3COO)(3) in oleic acid (OA) and oleylamine (OM). The uniform EuOF nanowires can self-organize on substrates to form parallel aligned superstructures and display strong Eu(3+)red emissions with high quantum yields of 65% under the UV light excitations due to the presence of dense surface Eu3+ sites in the ultrathin nanowires as well as the passivation of the surface defects by the capping ligands.

引用

页码：16364 / +

页数：4

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