Thermal behaviour studies of solid state compounds of cinnamylidenepyruvate with trivalent lanthanides and yttrium (III) in an atmosphere of CO2

被引:0
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作者
de Oliviera, JDS
Fertonani, FL
Melios, CB
Ionashiro, M
机构
[1] Univ Estadual Oeste Parana, Ctr Engn & Ciencias Exatas, BR-85903000 Toledo, PR, Brazil
[2] UNESP, Inst Quim, Dept Quim Analit, BR-14800900 Araraquara, SP, Brazil
来源
ECLETICA QUIMICA | 2002年 / 27卷
关键词
lanthanides; yttrium; cinnamylidenepyruvate; CO2; atmosphere; thermal behavior;
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学科分类号
摘要
Solid state cinnamylidenepyruvate of trivalent lanthanides (except for promethium) and yttrium, were prepared. Thermogravimetry, derivative thermogravimetry (TG, DTG), differential scanning calorimetry (DSC), X-ray diffraction powder patterns and complexometry were used to characterize and to study the thermal behavior of these compounds in a dynamic CO2 atmosphere. The results obtained showed significative differences on the thermal stability and thermal decomposition of these compounds, with regard to the thermal behavior study in a dynamic air atmosphere.
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页码:11 / 19
页数:9
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