Supramolecular Amphiphiles Based on a Water-Soluble Charge-Transfer Complex: Fabrication of Ultralong Nanofibers with Tunable Straightness

被引：155

作者：

Wang, Chao ^{[1
]}

Guo, Yinsheng ^{[1
]}

Wang, Yapei ^{[1
]}

Xu, Huaping ^{[1
]}

Wang, Ruji ^{[1
]}

Zhang, Xi ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 47期

基金：

中国国家自然科学基金;

关键词：

amphiphiles; charge transfer; nanostructures; self-assembly; supramolecular chemistry; SELF-ORGANIZATION; ELECTRON-TRANSFER; DONOR; RECOGNITION; ASSEMBLIES; NANOSTRUCTURES; DERIVATIVES; NANOWIRES;

D O I：

10.1002/anie.200903897

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From curly to straight: The formation of a charge-transfer complex is driven by the combination of Coulombic attraction and charge transfer interactions. The chargetransfer complex which is obtained from a supramolecular amphiphile (see picture) is water-soluble and forms ultralong nanofibers, the straightness of which can be modulated by changing the pH of the reaction solution. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8962 / 8965

页数：4

共 46 条

[1] 7,7,8,8-TETRACYANOQUINODIMETHANE AND ITS ELECTRICALLY CONDUCTING ANION-RADICAL DERIVATIVES [J].

ACKER, DS ;

HARDER, RJ ;

HERTLER, WR ;

MAHLER, W ;

MELBY, LR ;

BENSON, RE ;

MOCHEL, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (24) :6408-6409

[2] π-organogels of self-assembled p-phenylenevinylenes:: Soft materials with distinct size, shape, and functions [J].

Ajayaghosh, Ayyappanpillai ;

Praveen, Vakayil K. .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (08) :644-656

[3] Formation of oriented molecular nanowires on mica surface [J].

Akutagawa, T ;

Ohta, T ;

Hasegawa, T ;

Nakamura, T ;

Christensen, CA ;

Becher, J .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :5028-5033

[4]

[Anonymous], 2002, ANGEW CHEM

[5] Influence of intermolecular orientation on the photoinduced charge transfer kinetics in self-assembled aggregates of donor-acceptor arrays [J].

Beckers, EHA ;

Meskers, SCJ ;

Schenning, APHJ ;

Chen, ZJ ;

Würthner, F ;

Marsal, P ;

Beljonne, D ;

Cornil, J ;

Janssen, RAJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (02) :649-657

[6] Self-Assembled Nanofibers and Related Nanostructures from Molecular Rods [J].

Cho, Byoung-Ki ;

Kim, Ho-Joong ;

Chung, Yeon-Wook ;

Lee, Byung-Ill ;

Lee, Myongsoo .

SELF-ASSEMBLED NANOMATERIALS I: NANOFIBERS, 2008, 219 (01) :69-106

[7]

CUI S, 2006, ADV MATER, V18, P2918

[8] Fabrication and field-emission properties of large-area nanostructures of the organic charge-transfer complex Cu-TCNAQ [J].

Cui, Shuang ;

Li, Yuliang ;

Guo, Yanbing ;

Liu, Huibiao ;

Song, Yinglin ;

Xu, Jialiang ;

Lv, Jing ;

Zhu, Mei ;

Zhu, Daoben .

ADVANCED MATERIALS, 2008, 20 (02) :309-+

[9] Photophysical and photochemical properties of pyranine/methyl viologen complexes in solution and in supramolecular aggregates: A switchable complex [J].

de Borba, EB ;

Amaral, CLC ;

Politi, MJ ;

Villalobos, R ;

Baptista, MS .

LANGMUIR, 2000, 16 (14) :5900-5907

[10] ELECTRON-TRANSFER IN A NEW HIGHLY CONDUCTING DONOR-ACCEPTOR COMPLEX [J].

FERRARIS, J ;

WALATKA, V ;

PERLSTEI.JH ;

COWAN, DO .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (03) :948-949

← 1 2 3 4 5 →