From Ostwald Ripening to Single Chirality

被引：167

作者：

Noorduin, Wim L. ^{[3
]}

Vlieg, Elias ^{[3
]}

Kellogg, Richard M. ^{[2
]}

Kaptein, Bernard ^{[1
]}

机构：

[1] DSM Pharmaceut Prod, Innovat Synth & Catalysis, NL-6160 MD Geleen, Netherlands

[2] Syncom BV, NL-9747 AT Groningen, Netherlands

[3] Radboud Univ Nijmegen, IMM Solid State Chem, NL-6525 AJ Nijmegen, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 51期

关键词：

ablation; chiral resolution; conglomerates; crystallization; deracemization; ATTRITION-ENHANCED DERACEMIZATION; SYMMETRY-BREAKING; RESOLUTION; CRYSTALLIZATION; HOMOCHIRALITY; AMPLIFICATION; EMERGENCE; STATE;

D O I：

10.1002/anie.200905215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A century ago Wilhelm Ostwald received the Nobel Prize for Chemistry. Although Ostwald was never significantly involved with the phenomenon of chirality, one of his discoveries, Ostwald ripening, is thought to be involved in a recently discovered method in which grinding-induced attrition is used to transform racemic conglomerates virtually quantitatively into a single enantiomer. In this Minireview the basic concepts developed by Ostwald will be introduced, followed by a summary of the current status of grinding-induced asymmetric transformations. We will see how close Ostwald himself came to discovering this technique. © 2009 Wiley-VCH Verlag GmbH &. Co. KCaA.

引用

页码：9600 / 9606

页数：7

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