Sensing mechanism of Ag/α-MoO3 nanobelts for H2S gas sensor

被引:47
作者
Shen, Shi-Kai [1 ]
Cui, Xin-Lei [1 ]
Guo, Chuan-Yu [2 ]
Dong, Xin [3 ]
Zhang, Xian-Fa [2 ]
Cheng, Xiao-Li [2 ]
Huo, Li-Hua [2 ]
Xu, Ying-Ming [2 ]
机构
[1] Suihua Univ, Sch Elect Engn, Suihua 152000, Peoples R China
[2] Heilongjiang Univ, Key Lab Funct Inorgan Mat Chem, Minist Educ Peoples Republ China, Harbin 150080, Peoples R China
[3] Sun Yat Sen Univ, Guangdong Engn Technol Res Ctr High Performance O, Sch Chem, Key Lab Polymer Composite & Funct Mat,Minist Educ, Guangzhou 510275, Peoples R China
基金
中国国家自然科学基金;
关键词
Ag/alpha-MoO3; Nanobelt; Gas sensor; Hydrogen sulfide; Sensing mechanism; MOO3; ALPHA-FE2O3; NANOSHEETS; PERFORMANCE; COMPOSITES; MOS2;
D O I
10.1007/s12598-020-01647-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sensing mechanism is still a big problem in the field of gas sensor. In-depth study of the sensing mechanism can provide better ideas for the design of sensing materials, and it is also more conducive to the improvement in gas-sensing performance. In this work, Ag/alpha-MoO3 material was obtained by loading Ag in alpha-MoO3 nanobelts prepared by hydrothermal method. The material was characterized by field electron scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Comparing the gas sensing properties of alpha-MoO3 and Ag/alpha-MoO3, it is found that Ag effectively improves the selectivity of the material to H2S at 133 degrees C. The response of the 5 wt% Ag/alpha-MoO3 sensor to 100 x 10(-6) hydrogen sulfide (H2S) is 225 and the detection limit is 100 x 10(-9). The sensing mechanism was verified by gas chromatography and mass spectrometer (GC-MS), XPS and Fourier transform infrared spectroscopy (FTIR).
引用
收藏
页码:1545 / 1553
页数:9
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