HI-catalyzed hydroamination and hydroarylation of alkenes

被引：47

作者：

Marcsekova, Klaudia

Doye, Sven

机构：

[1] Univ Oldenburg, Inst Reine & Angew Chem, D-26111 Oldenburg, Germany

[2] Univ Heidelberg, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

SYNTHESIS-STUTTGART | 2007年 / 01期

关键词：

alkenes; aminations; amines; homogeneous catalysis; iodine;

D O I：

10.1055/s-2006-958934

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic amines react with alkenes in the presence of catalytic amounts of aqueous HI to give mixtures of the corresponding hydroamination and hydroarylation products. While the bydroamination reaction is the preferred pathway for aliphatic alkenes, the hydroarylation reaction becomes more important when styrenes are used as substrates. In general, the electronic properties of the alkene and the amine strongly influence the efficiency and the selectivity of the reaction.

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收藏

页码：145 / 154

页数：10

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