Template-Free Hydrothermal Synthesis and Photocatalytic Performances of Novel Bi2SiO5 Nanosheets

被引:97
|
作者
Chen, Ruigen [1 ]
Bi, Jinhong [1 ]
Wu, Ling [1 ,2 ]
Wang, Wanjun [1 ]
Li, Zhaohui [1 ]
Fu, Xianzhi [1 ]
机构
[1] Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Breeding Base Pholocatalysis, Fuzhou 350002, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
基金
中国国家自然科学基金;
关键词
P-BLOCK METAL; WATER DECOMPOSITION; THIN-FILMS; NANOSTRUCTURE; DEGRADATION; MORPHOLOGY; EVOLUTION;
D O I
10.1021/ic901084s
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Orthorhombic Bi2SiO5 nanosheets with thicknesses of 10-20 nm were first synthesized by a template-free hydrothermal synthesis process using Bi(NO3)(3) and different Si sources as raw materials. The as-prepared samples were characterized by X-ray diffraction, Brunauer-Emmett-Teller (BET) surface area analysis, UV-vis diffuse reflectance spectroscopy, scanning electron microscopy, high-resolution transmission electron microscopy, and a photoluminescence technique with terephthalic acid. The results showed that different precursors led to samples with different morphologies, particle sizes, and BET surface areas, As a novel photocatalyst, the photocatalytic performances of Bi2SiO5 samples were evaluated by the photocatalytic degradation of salicylic acid and gaseous benzene. The results revealed that the sample obtained from Na2SiO3 as a precursor exhibited higher activity than that from (C2H5O)(4)Si due to its biscuit-like morphology, a smaller particle size, and a higher BET surface areas.
引用
收藏
页码:9072 / 9076
页数:5
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