High heat sink jet fuels. 2. Stabilization of a JP-8 with model refined chemical oil/light cycle oil (RCO/LCO)-derived stabilizers

被引:14
作者
Sobkowiak, Maria
Clifford, Caroline Burgess
Beaver, Bruce [1 ]
机构
[1] Penn State Univ, Energy Inst, University Pk, PA 16802 USA
[2] Duquesne Univ, Dept Chem & Biochem, Pittsburgh, PA 15282 USA
关键词
D O I
10.1021/ef060422f
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
JP-900 is the generic name given to a future jet fuel that will be required to handle an anticipated thermal stress of similar to 900 degrees F (482 degrees C) for several hours. We report flowing rig scouting results, under approximate JP-900 conditions, examining the effect on both oxidative and pyrolytic stability of the addition of a few volume percent of model refined chemical oil/light cycle oil (RCO/LCO)-derived compounds to a petroleum-derived JP-8. Tetralin, tetralone, and tetralol were used as model hydroaromatic compounds, which, in principle, can be obtained via the hydrotreatment of RCO/LCO blends. Our scouting results suggest that a jet fuel with improved heat sink capabilities could likely be formulated by adding 1% v/v of hydroaromatic compounds to JP-8.
引用
收藏
页码:982 / 986
页数:5
相关论文
共 29 条
[1]  
[Anonymous], 1996, Petroleum Chemistry Devision Preprints
[2]  
BALSTER LM, 2005, UNPUB FUEL PROCESS T
[3]   Analysis of polar species in jet fuel and determination of their role in autoxidative deposit formation [J].
Balster, Lori M. ;
Zabarnick, Steven ;
Striebich, Richard C. ;
Shafer, Linda M. ;
West, Zachary J. .
ENERGY & FUELS, 2006, 20 (06) :2564-2571
[4]   On the mechanisms of formation of thermal oxidative deposits in jet fuels. Are unified mechanisms possible for both storage and thermal oxidative deposit formation for middle distillate fuels? [J].
Beaver, B ;
Gao, L ;
Burgess-Clifford, C ;
Sobkowiak, M .
ENERGY & FUELS, 2005, 19 (04) :1574-1579
[5]  
BEAVER B, 2007, ENERGY FUELS, V21
[6]   Model studies examining the use of dicyclohexylphenylphosphine to enhance the oxidative and thermal stability of future jet fuels [J].
Beaver, BD ;
Gao, L ;
Fedak, MG ;
Coleman, MM ;
Sobkowiak, M .
ENERGY & FUELS, 2002, 16 (05) :1134-1140
[7]   High heat sink jet fuels. Part 1. Development of potential oxidative and pyrolytic additives for JP-8 [J].
Beaver, Bruce D. ;
Clifford, Caroline Burgess ;
Fedak, Mitchel G. ;
Gao, Li ;
Iyer, Pravin S. ;
Sobkowiak, Maria .
ENERGY & FUELS, 2006, 20 (04) :1639-1646
[8]  
BUTNARK S, 2001, PREPR PAP AM CHEM SO, V45, P493
[9]   POTENTIAL STABILIZERS FOR JET FUELS SUBJECTED TO THERMAL-STRESS ABOVE 400-DEGREES-C [J].
COLEMAN, MM ;
SELVARAJ, L ;
SOBKOWIAK, M ;
YOON, E .
ENERGY & FUELS, 1992, 6 (05) :535-539
[10]  
COLEMAN MM, 1998, PREPR PAP AM CHEM SO, V43, P353