Gravure printed PEDOT: PSS as anode for flexible ITO-free organic light emitting diodes

被引:20
作者
Montanino, M. [1 ]
Sico, G. [1 ]
Prontera, C. T. [1 ]
Del Mauro, A. De Girolamo [1 ]
Aprano, S. [1 ]
Maglione, M. G. [1 ]
Minarini, C. [1 ]
机构
[1] ENEA Italian Natl Agcy New Technol Energy & Susta, Portici Res Ctr, Piazzale E Fermi 1, I-80055 Portici, NA, Italy
关键词
industrial applications; PEDOT:PSS; ITO-free; flexible organic light emitting diode; gravure printing; ELECTRODES;
D O I
10.3144/expresspolymlett.2017.48
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Roll-to-roll gravure printing is considered as potential leading manufacturing technology for flexible, low cost and large area optoelectronics. However, solution processed multilayer organic electronics are still challenging to be produced, especially in the case of electrodes. In this work, the gravure printing technique was successfully employed to realize the highly conductive poly(3,4ethylenedioxythiophene): poly(styrene sulfonate) (PEDOT: PSS) polymeric anode and tested for the first time in flexible ITO-free (Indium Thin Oxide) organic light emitting diodes (OLEDs). The device performances were found to be similar to those of a reference device containing a spin-coated polymeric anode. A gravure printed dimethyl sulfoxide (DMSO) post-treatment was successfully tried to improve the printed anode characteristics. The obtained results show the way for future development for processing flexible ITO-free devices using the most attractive printing technology for roll-to-roll large area manufacturing.
引用
收藏
页码:518 / 523
页数:6
相关论文
共 20 条
[1]   High performance, flexible polymer light-emitting diodes (PLEDs) with gravure contact printed hole injection and light emitting layers [J].
Chung, Dae-Young ;
Huang, Jingsong ;
Bradley, Donal D. C. ;
Campbell, Alasdair J. .
ORGANIC ELECTRONICS, 2010, 11 (06) :1088-1095
[2]   Study of the effect of the doped poly(3,4-ethylenedioxythiophene): poly(styrene sulfonate) polymeric anode on the organic light-emitting diode performances [J].
Del Mauro, Anna De Girolamo ;
Nenna, Giuseppe ;
Villani, Fulvia ;
Minarini, Carla .
THIN SOLID FILMS, 2012, 520 (16) :5386-5391
[3]  
Grau G., 2016, FLEXIBLE PRINTED ELE, P1
[4]   Effects of solution-processed polymer interlayers on hole injection and device performance of polymer light-emitting diodes [J].
Harding, M. James ;
Poplavskyy, Dmitry ;
Choong, V. -E. ;
Campbell, Alasdair J. ;
So, Franky .
ORGANIC ELECTRONICS, 2008, 9 (02) :183-190
[5]   The Compromises of Printing Organic Electronics: A Case Study of Gravure-Printed Light-Emitting Electrochemical Cells [J].
Hernandez-Sosa, Gerardo ;
Tekoglu, Serpil ;
Stolz, Sebastian ;
Eckstein, Ralph ;
Teusch, Claudia ;
Trapp, Jannik ;
Lemmer, Uli ;
Hamburger, Manuel ;
Mechau, Norman .
ADVANCED MATERIALS, 2014, 26 (20) :3235-+
[6]   An approach for controlling printed line-width in high resolution roll-to-roll gravure printing [J].
Ho Anh Duc Nguyen ;
Lee, Jongsu ;
Kim, Chung Hwan ;
Shin, Kee-Hyun ;
Lee, Dongjin .
JOURNAL OF MICROMECHANICS AND MICROENGINEERING, 2013, 23 (09)
[7]   High efficient plastic solar cells fabricated with a high-throughput gravure printing method [J].
Kopola, P. ;
Aernouts, T. ;
Guillerez, S. ;
Jin, H. ;
Tuomikoski, M. ;
Maaninen, A. ;
Hast, J. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (10) :1673-1680
[8]   Gravure printed organic light emitting diodes for lighting applications [J].
Kopola, P. ;
Tuomikoski, M. ;
Suhonen, R. ;
Maaninen, A. .
THIN SOLID FILMS, 2009, 517 (19) :5757-5762
[9]   Characterization of thermal annealing of gravure printed PVK/Ir(ppy)3 organic light emitting layers [J].
Lee, Hyemi ;
Kim, Aran ;
Cho, Sung Min ;
Chae, Heeyeop .
CURRENT APPLIED PHYSICS, 2010, 10 (04) :E143-E146
[10]   Process optimization of gravure printed light-emitting polymer layers by a neural network approach [J].
Michels, Jasper J. ;
de Winter, Suzanne H. P. M. ;
Symonds, Laurence H. G. .
ORGANIC ELECTRONICS, 2009, 10 (08) :1495-1504