Cyclohexane and toluene oxidation catalyzed by 1,10-phenantroline Cu(II) complexes

被引：28

作者：

Detoni, Chaline ^{[2
,3
]}

Carvalho, Nakedia M. F. ^{[2
]}

Aranda, Donato A. G. ^{[3
]}

Louis, B. ^{[1
]}

Antunes, O. A. C. ^{[2
]}

机构：

[1] Univ Strasbourg, LMSPC, CNRS, UMR 7515,Part European Lab Catalysis & Surface Sc, F-67087 Strasbourg 2, France

[2] Univ Fed Rio de Janeiro, Inst Quim, BR-21945970 Rio De Janeiro, Brazil

[3] Univ Fed Rio de Janeiro, Escola Quim, BR-21941909 Rio De Janeiro, Brazil

来源：

APPLIED CATALYSIS A-GENERAL | 2009年 / 365卷 / 02期

关键词：

Selective cyclohexane oxidation; Mononuclear Cu(II) complexes; 1,10-Phenantroline; Peroxides; Cyclic voltammetry; COPPER(II) COMPLEXES; MOLECULAR-OXYGEN; IRON(III);

D O I：

10.1016/j.apcata.2009.06.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work, we present the cyclohexane oxidation catalyzed by the mononuclear 1,10-phenantroline Cu(II) complexes: [Cu(phen)(3)]Cl-2 center dot 7H(2)O (1), [Cu(phen)(2)Cl]Cl center dot 5H(2)O (2), [Cu(phen)Cl-2] (3), using hydrogen peroxide as oxidant, in acetonitrile:water (3.5:1) solution. The reactions were carried out at temperatures ranging from 25 degrees C to 70 degrees C. All complexes were able to oxidize cyclohexane into cyclohexanol and cyclohexanone with low to moderate yields. Adipic acid was also formed in the reaction. The highest conversion was obtained with the system [Cu(phen)(2)Cl]Cl/H2O2/70 degrees C, with 67% total yield. Furthermore, these complexes were also able to oxidize toluene at room temperature. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：281 / 286

页数：6

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