Dynamic resolution of α-halo carboxylic acid derivatives in asymmetric nucleophilic substitution using chiral auxiliaries

被引：18
作者：
Park, Yong Sun [1 ]
机构：
[1] Konkuk Univ, Dept Chem, Seoul 143701, South Korea
来源：
TETRAHEDRON-ASYMMETRY | 2009年 / 20卷 / 21期
关键词：
N-METHYL PSEUDOEPHEDRINE; DIACETONE-D-GLUCOSE; KINETIC RESOLUTION; UTILIZING; 2-OXOIMIDAZOLIDINE-4-CARBOXYLATE; BROMO AMIDES; STEREOSELECTIVE-SYNTHESIS; THERMODYNAMIC RESOLUTION; AMINO ESTERS; RATIONALIZING DIASTEREOSELECTION; STEREOSPECIFIC AMINATION;
D O I：
10.1016/j.tetasy.2009.10.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Recent results on the chiral auxiliary-mediated dynamic resolution of alpha-halo acid derivatives in nucleophilic substitution have been outlined and classified into two major mechanistic categories, dynamic thermodynamic resolution (DTR) and dynamic kinetic resolution (DKR). Asymmetric nucleophilic substitution of alpha-halo acid derivatives with various nitrogen, oxygen, sulfur, and carbon nucleophiles is widely used for the stereoselective preparation of alpha-substituted carboxylic acids. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2421 / 2427
页数：7
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