A new MOF-505 analog exhibiting high acetylene storage

被引：231

作者：

Hu, Yunxia ^{[1
]}

Xiang, Shengchang ^{[2
]}

Zhang, Wenwei ^{[1
]}

Zhang, Zhuxiu ^{[1
]}

Wang, Lei ^{[1
]}

Bai, Junfeng ^{[1
]}

Chen, Banglin ^{[2
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 48期

关键词：

METAL-ORGANIC FRAMEWORKS; HIGH H-2 ADSORPTION; HYDROGEN ADSORPTION; SORPTION PROPERTIES; AIR SEPARATION; SITES; FUNCTIONALIZATION; POROSITY; LEAD; SIZE;

D O I：

10.1039/b917046d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new microporous metal-organic framework Cu-2(EBTC)(H2O)(2)center dot xG (EBTC = 1,1'-ethynebenzene-3,3',5,5'-tetracarboxylate; G = guest molecule) was rationally designed with a NbO net, exhibiting significantly high acetylene storage of 252 and 160 cm(3) g(-1) at 273 and 295 K under 1 bar, respectively.

引用

页码：7551 / 7553

页数：3

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