Third-order optical nonlinearity of Cu nanoparticle-dispersed Ba0.5Sr0.5TiO3 films prepared by alternating pulsed laser deposition

被引:22
作者
Kim, Ji-Suk
Lee, Kyeong-Seok
Kim, Sang Sub [1 ]
机构
[1] Chonnam Natl Univ, Dept Mat Sci & Engn, Kwangju 500757, South Korea
[2] Korea Inst Sci & Technol, Thin Film Mat Res Ctr, Seoul 136791, South Korea
关键词
nanocomposites; nonlinear optical properties; pulse laser deposition; copper; barium; strontium; titanate;
D O I
10.1016/j.tsf.2006.03.058
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanocomposite thin films consisting of nanometer-sized Cu particles embedded in an amorphous Ba0.5Sr0.5TiO3 matrix (Cu:BST) on Al2O3 (0001) substrates were fabricated by an alternating pulsed laser deposition method. The nanocomposite films containing Cu nanoparticles with a volume fraction of more than 5.4% showed a characteristic surface plasmon resonance (SPR) absorption band at similar to 580 nm. The nonlinear optical properties of the Cu:BST nanocomposite film with a Cu volume faction of 5.4% were determined using the Z-scan method at the SPR wavelength. The magnitude of the third-order nonlinear susceptibility of the sample was calculated to be 9.737 x 10(-9) esu. (c) 2006 Elsevier B.V All rights reserved.
引用
收藏
页码:2332 / 2336
页数:5
相关论文
共 28 条
[1]   Pulsed laser deposition of Cu:Al2O3 nanocrystal thin films with high third-order optical susceptibility [J].
Ballesteros, JM ;
Serna, R ;
Solis, J ;
Afonso, CN ;
PetfordLong, AK ;
Osborne, DH ;
Haglund, RF .
APPLIED PHYSICS LETTERS, 1997, 71 (17) :2445-2447
[2]   On the optical absorption and nonlinearity of silica films containing metal nanoparticles [J].
Cattaruzza, E ;
Battaglin, G ;
Gonella, F ;
Polloni, R ;
Mattei, G ;
Maurizio, C ;
Mazzoldi, P ;
Sada, C ;
Montagna, M ;
Tosello, C ;
Ferrari, M .
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 2002, 82 (06) :735-744
[3]   Metal nanoclusters in glasses as non-linear photonic materials [J].
Chakraborty, P .
JOURNAL OF MATERIALS SCIENCE, 1998, 33 (09) :2235-2249
[4]   Growth behavior and optical properties of metal-nanoparticle dispersed dielectric thin films formed by alternating sputtering [J].
Cho, SH ;
Lee, S ;
Ku, DY ;
Lee, TS ;
Cheong, B ;
Kim, WM ;
Lee, KS .
THIN SOLID FILMS, 2004, 447 :68-73
[5]   Spectroellipsometric characterization of plasma-deposited Au/SiO2 nanocomposite films [J].
Dalacu, D ;
Martinu, L .
JOURNAL OF APPLIED PHYSICS, 2000, 87 (01) :228-235
[6]   Annealing behavior of silver, copper, and silver-copper nanoclusters in a silica matrix synthesized by the sol-gel technique [J].
De, G ;
Gusso, M ;
Tapfer, L ;
Catalano, M ;
Gonella, F ;
Mattei, G ;
Mazzoldi, P ;
Battaglin, G .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (12) :6734-6739
[7]   Third order nonlinear optical susceptibility of Cu:Al2O3 nanocomposites:: From spherical nanoparticles to the percolation threshold [J].
del Coso, R ;
Requejo-Isidro, J ;
Solis, J ;
Gonzalo, J ;
Afonso, CN .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (05) :2755-2762
[8]  
Flytzanis C., 1991, NONLINEAR OPTICS COM
[9]   Optical properties of nanostructured optical materials [J].
Gehr, RJ ;
Boyd, RW .
CHEMISTRY OF MATERIALS, 1996, 8 (08) :1807-1819
[10]   OPTICAL NONLINEARITIES OF SMALL METAL PARTICLES - SURFACE-MEDIATED RESONANCE AND QUANTUM SIZE EFFECTS [J].
HACHE, F ;
RICARD, D ;
FLYTZANIS, C .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1986, 3 (12) :1647-1655