Crystal and molecular structure of di-tert-butylhydridosilanol

被引:8
作者
Beckmann, J [1 ]
Jurkschat, K [1 ]
Schürmann, M [1 ]
机构
[1] Univ Dortmund, Lehrstuhl Anorgan Chem 2, D-44221 Dortmund, Germany
关键词
silicon; silanol; hydrogen bonding; X-ray structure;
D O I
10.1016/S0022-328X(00)00152-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The single-crystal X-ray structure analysis is reported of t-Bu2SiH(OH). In the crystal lattice, four molecules of the title compound are connected via hydrogen bridges showing an eight-membered O4H4 ring structural motif. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:170 / 172
页数:3
相关论文
共 25 条
[1]   HYDROGEN-BONDING INTERACTION BETWEEN A HYDROXY GROUP AND THE PI-ELECTRONS OF AN ARYL GROUP - CRYSTAL-STRUCTURE OF [TRIS(DIMETHYLPHENYLSILYL)METHYL]METHYLSILANOL [J].
ALJUAID, SS ;
ALNASR, AKA ;
EABORN, C ;
HITCHCOCK, PB .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (20) :1482-1484
[2]  
[Anonymous], 1995, ANGEW CHEM, V107, P2541
[3]   UNEXPECTED CHEMISTRY IN AN ATTEMPTED GENERATION OF A STERICALLY HINDERED SILENE [J].
BARTON, TJ ;
TULLY, CR .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 172 (01) :11-19
[4]   On the reaction of [Ph-2(OH)Si](2)O with t-Bu2SnCl2: synthesis and characterization of the first well defined polystannasiloxane [(t-Bu2SnO)(Ph2SiO)(2)](n) [J].
Beckmann, J ;
Jurkschat, K ;
Schollmeyer, D ;
Schurmann, M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 543 (1-2) :229-232
[5]   Reaction of (t-Bu2SnO)3 with organohalosilanes.: Simple formation of open-chain and cyclic stannasiloxanes [J].
Beckmann, J ;
Mahieu, B ;
Nigge, W ;
Schollmeyer, D ;
Schürmann, M ;
Jurkschat, K .
ORGANOMETALLICS, 1998, 17 (26) :5697-5712
[6]   Strained metallastannoxanes-ring-opening polymerization versus retention of six-membered-ring structure [J].
Beckmann, J ;
Jurkschat, K ;
Kaltenbrunner, U ;
Pieper, N ;
Schürmann, M .
ORGANOMETALLICS, 1999, 18 (09) :1586-1595
[7]  
Beckmann J, 1998, MAIN GROUP MET CHEM, V21, P113
[8]   Reactions of [t-Bu2SnO]3 with [t-BuX2Si]2 (X = F, Cl).: Syntheses and structures of novel stannasiloxanes and of [(t-Bu2FSn)2O]2, the first fluorine-containing tetraorganodistannoxane [J].
Beckmann, J ;
Biesemans, M ;
Hassler, K ;
Jurkschat, K ;
Martins, JC ;
Schurmann, M ;
Willem, R .
INORGANIC CHEMISTRY, 1998, 37 (19) :4891-4897
[9]   1,1,3,3,5,5,7,7-octaphenyl-1,3,5,7-tetrasiloxane-1,7-diol and its organotin derivatives.: Model compounds for diphenylsiloxane polymer [J].
Beckmann, J ;
Jurkschat, K ;
Müller, D ;
Rabe, S ;
Schürmann, M .
ORGANOMETALLICS, 1999, 18 (12) :2326-2330
[10]   THE CRYSTAL-STRUCTURE OF TERT-BU2SI(OH)F - A CYCLIC HYDROGEN-BONDED TETRAMER [J].
BUTTRUS, NH ;
EABORN, C ;
HITCHCOCK, PB ;
SAXENA, AK .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 287 (02) :157-161