Volumetric and acoustic properties of amino acids L-Leucine and L-Serine in aqueous solution of ammonium dihydrogen phosphate (ADP) at different temperatures and concentrations

被引:21
作者
Kumar, Harsh [1 ]
Kumar, Vaneet [2 ,3 ]
Sharma, Seema [2 ,4 ]
Katal, Arjuna [1 ]
Alothman, Asma A. [5 ]
机构
[1] Dr BR Ambedkar Natl Inst Technol, Dept Chem, Jalandhar 144011, Punjab, India
[2] IKG Panjab Tech Univ, Kapurthala Rd, Jalandhar, Punjab, India
[3] CT Grp Inst, Dept Appl Sci, CTIEMT, Jalandhar, Punjab, India
[4] MRPD Govt Arts & Sci Coll, Talwara 144216, Punjab, India
[5] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
关键词
Density; Speed of sound; Apparent molar volume; Solute-solvent interaction; Ammonium dihydrogen phosphate; Amino acids;
D O I
10.1016/j.jct.2020.106350
中图分类号
O414.1 [热力学];
学科分类号
摘要
The physicochemical properties of amino acids like L-Leucine and L-Serine in aqueous solution of ammonium dihydrogen Phosphate (ADP) at different temperature analysed by volumetric and acoustic methods. By using density data, apparent molar volume V-phi, partial molar volume V-phi(0) and standard partial molar volume of transfer Delta V(phi)(0 )have been evaluated. From speed of sound data, apparent molar isentropic compression K-phi,K-s apparent partial molar isentropic compression K-phi,s(0) and partial molar isentropic compression of transfer Delta K-phi,s(0) have been calculated. The pair and triplet interaction coefficient have also been calculated. The results have been interpreted in terms of solute-solute and solvent-solvent interactions. (C) 2020 Elsevier Ltd.
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页数:14
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