A Comprehensive Chemical Model for the Splitting of CO2 in Non-Equilibrium Plasmas

被引：54

作者：

Koelman, Peter ^{[1
]}

Heijkers, Stijn ^{[2
]}

Mousavi, Samaneh Tadayon ^{[1
]}

Graef, Wouter ^{[3
]}

Mihailova, Diana ^{[3
]}

Kozak, Tomas ^{[4
,5
]}

Bogaerts, Annemie ^{[2
]}

van Dijk, Jan ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Dept Appl Phys, POB 513, NL-5600 MB Eindhoven, Netherlands

[2] Univ Antwerp, Dept Chem, PLASMANT, Campus Drie Eiken,Univ Pl 1, B-2610 Antwerp, Belgium

[3] Plasma Matters BV, Den Dolech 2 Flux 3-112, NL-5612 AZ Eindhoven, Netherlands

[4] Univ West Bohemia, Dept Phys, Univ 8, Plzen 30614, Czech Republic

[5] Univ West Bohemia, NTIS European Ctr Excellence, Univ 8, Plzen 30614, Czech Republic

来源：

PLASMA PROCESSES AND POLYMERS | 2017年 / 14卷 / 4-5期

关键词：

CO2; modeling; non-equilibrium; verification; vibrational modes; ELECTRON-TRANSPORT COEFFICIENTS; CROSS-SECTIONS; IMPACT IONIZATION; GAS-MIXTURE; OXYGEN; OZONE; DECOMPOSITION; TEMPERATURE; DISSOCIATION; CO2-LASERS;

D O I：

10.1002/ppap.201600155

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

An extensive CO2 plasmamodel is presented that is relevant for the production of "solar fuels.'' It is based on reaction rate coefficients fromrigorously reviewed literature, and is augmentedwith reactionrate coefficients that are obtained fromscaling laws. The input data set, whichis suitable for usage with the plasma simulation software Plasimo (https://plasimo.phys.tue.nl/), is available via the Plasimo and publisher's websites. 1 The correctness of this model implementation has been established by independent ZDPlasKin implementation (http://www.zdplaskin. laplace.univ-tlse.fr/), to verify that the results agree. Results of these "global models'' are presented for a DBD plasma reactor.

引用

页数：20

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