Luminescence detection of open-shell transition-metal ions by photoinduced electron transfer controlled by internal charge transfer of a receptor

被引：83

作者：

Schwarze, Thomas ^{[1
]}

Mueller, Holger ^{[1
]}

Dosche, Carsten ^{[1
]}

Klamroth, Tillmann ^{[1
]}

Mickler, Wulfhard ^{[1
]}

Kelling, Alexandra ^{[1
]}

Loehmannsroeben, Hans-Gerd ^{[1
]}

Saalfrank, Peter ^{[1
]}

Holdt, Hans-Juergen ^{[1
]}

机构：

[1] Univ Potsdam, Inst Chem, D-14476 Golm, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 10期

关键词：

charge transfer; electron transfer; fluorescence; palladium; sensors;

D O I：

10.1002/anie.200603992

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) When push comes to shove: The oxidative photoinduced electron transfer (PET) in anthrylmethylthiomaleonitrile derivatives is regulated by the intramolecular charge transfer (ICT) of the "push-pull" dithiomaleonitrile receptor. Selective complexation with palladium chloride switches off the ICT, stops the PET, and results in fluorescence enhancement (see picture). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1671 / 1674

页数：4

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