Catalytic combustion of methane in the presence of organic and inorganic compounds over La0.9Ce0.1CoO3 catalyst

被引:19
作者
Auer, R
Alifanti, M
Delmon, B
Thyrion, FC
机构
[1] Catholic Univ Louvain, Inst Chem Engn, B-1348 Louvain, Belgium
[2] Catholic Univ Louvain, Unite Catalyse & Chim Mat Div, B-1348 Louvain, Belgium
关键词
coke oven emission; perovskite catalyst; methane combustion; mixture effect;
D O I
10.1016/S0926-3373(02)00125-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The catalytic combustion of the emission from coke ovens containing various volatile organic compounds (VOCs) and inorganic species over a La0.9Ce0.1CoO3 catalyst is investigated in an integral fixed reactor through several steps. (1) Combustion of a mixture of VOC reveals that the kinetics of total oxidation of methane determines the total VOC conversion. (2) The conversion of methane, in the case of sulfur-free feed is inhibited by H2O and CO2. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:311 / 318
页数:8
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