Spectroscopic and microscopic properties of KSrVO4: Mn2+ synthesized by low-cost combustion method

被引:7
作者
Sharma, Parul [1 ]
Singh, Pragati [2 ]
Kamni [1 ]
机构
[1] Shri Mata Vaishno Devi Univ, Sch Phys, Katra 182320, JK, India
[2] Indian Inst Technol BHU, Dept Phys, Varanasi, Uttar Pradesh, India
关键词
Vanadates; Combustion synthesis; X-ray diffraction (XRD); Photoluminescence; Transmission electron microscopy (TEM); UV-Vis spectroscopy; LUMINESCENCE PROPERTIES; LIGHT-EMISSION; PHOSPHOR;
D O I
10.1016/j.physb.2020.412500
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
This paper reports the systematic study of Mn2+ doped KSrVO4 nanophosphors synthesized by low-cost combustion method. X-Ray Diffraction, UV-Vis spectroscopy, Photoluminescence (PL) spectroscopy, Scanning Electron Microscopy (SEM), Energy Dispersive Analysis of X-rays (EDAX) and Transmission Electron Microscopy (TEM) revealed the structural and spectral properties of synthesized powders. By doping Mn2+ into the host, it is observed that for small concentration of Mn2+ the band gap decreases initially showing the red shift followed by increase in band gap for higher concentration of Mn2+. PL spectra exhibits two prominent emission peaks at 436 nm and 511 nm under 373 nm excitation. The synthesized nanophosphor powders may perhaps be thought of as new phosphor materials excited by UVA emitting InGaN LEDs.
引用
收藏
页数:9
相关论文
共 32 条
[1]   Synthesis and crystal structure of a noncentrosymmetric form of potassium strontium monovanadate KSrVO4 [J].
Azrour, M ;
El Ammari, L ;
Le Fur, Y ;
Elouadi, B .
MATERIALS RESEARCH BULLETIN, 2000, 35 (02) :263-270
[2]   Tuning the bandgap of ZnO by substitution with Mn2+, Co2+ and Ni2+ [J].
Bhat, SV ;
Deepak, FL .
SOLID STATE COMMUNICATIONS, 2005, 135 (06) :345-347
[3]   Potential of Sm3+ doped LiSrVO4 nanophosphor to fill amber gap in LEDs [J].
Biswas, P. ;
Kumar, Vinay ;
Sharma, Vishal ;
Bedyal, A. K. ;
Padha, Naresh ;
Swart, H. C. .
PHYSICA B-CONDENSED MATTER, 2018, 535 :221-226
[4]   Enhanced orange-red emission from KSrVO4:Sm3+ nanophosphor for possible application in blue light-emitting diode based white LED [J].
Biswas, P. ;
Kumar, Vinay ;
Ntwaeaborwa, O. M. ;
Swart, H. C. .
MATERIALS RESEARCH EXPRESS, 2015, 2 (02)
[5]   THE VALIDITY OF THE USE OF SEM/EDAX AS A TOOL FOR THE DETECTION OF UF RESIN PENETRATION INTO WOOD CELL-WALLS IN PARTICLEBOARD [J].
BOLTON, AJ ;
DINWOODIE, JM ;
DAVIES, DA .
WOOD SCIENCE AND TECHNOLOGY, 1988, 22 (04) :345-356
[6]   Synthesis, energy transfer and luminescence properties of KSrVO4:Eu3+ red phosphor [J].
Cao, Renping ;
Peng, Dedong ;
Fu, Ting ;
Luo, Zhiyang ;
Zhou, Shenlin ;
Jiang, Shenhua ;
Fu, Jingwei .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2016, 27 (08) :8094-8099
[7]  
E.W. POWD, 1989, INT POWD DIFFR DAT I, P5042
[8]   White Light Emission from Planar Remote Phosphor Based on NHC Cycloplatinated Complexes [J].
Fuertes, Sara ;
Chueca, Andres J. ;
Peralvarez, Mariano ;
Borja, Pilar ;
Torrell, Marc ;
Carreras, Josep ;
Sicilia, Violeta .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (25) :16160-16169
[9]   An oxide-diluted magnetic semiconductor: Mn-doped ZnO [J].
Fukumura, T ;
Jin, ZW ;
Ohtomo, A ;
Koinuma, H ;
Kawasaki, M .
APPLIED PHYSICS LETTERS, 1999, 75 (21) :3366-3368
[10]   Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films [J].
Hassanien, A. S. ;
Akl, Alaa A. .
SUPERLATTICES AND MICROSTRUCTURES, 2016, 89 :153-169