Synthesis of [Ti(eta(6)-1,3,5-(C6H3Pr3)-Pr-i)(2)][BAr4] (Ar=C6H5, p-C6H4F, 3,5-C6H3(CF3)(2)), the first titanium(I) derivatives

被引：20

作者：

Calderazzo, F

Ferri, I

Pampaloni, G

Englert, U

Green, MLH

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

[2] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,D-52074 AACHEN,GERMANY

[3] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 14期

关键词：

D O I：

10.1021/om970155o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxidation of Ti(eta(6)-1,3,5-(C6H3Pr3)-Pr-i)(2) with FeCp2[BAr4], Ar = C6H5, p-C6H4F, 3,5-C6H3(CF3)(2), affords good yields of the paramagnetic derivatives of titanium(I), [Ti(eta(6)-1,3,5-(C6H3Pr3)-Pr-i)(2)][BAr4]; these compounds have been characterized by conventional methods, including single-crystal X-ray diffractometry of [Ti(eta(6)-1,3,5-(C6H3Pr3)-Pr-i)(2)][B(p-C6H4F)(4)].

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页码：3100 / 3101

页数：2

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