AIR-WATER INTERFACE Faster chemistry at surfaces

被引:6
|
作者
Walker, Robert A. [1 ]
机构
[1] Montana State Univ, Montana Mat Sci Program, Dept Chem & Biochem, Bozeman, MT 59717 USA
关键词
TIME-SCALES;
D O I
10.1038/s41557-021-00672-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The physical properties of a liquid at an interface differ from bulk solution limits, but how this affects chemical reactivity is unclear. Now, ultrafast, surface-sensitive vibrational spectroscopy has revealed that the light-induced reaction of phenol with water is four orders of magnitude faster at the water surface than in bulk.
引用
收藏
页码:296 / 297
页数:2
相关论文
共 50 条
  • [1] Chemistry at the interface: Chemical transformations at the air-water interface
    Ehrenhauser, Franz S.
    Heath, Aubrey A.
    Liyana-Arachchi, Thilanga P.
    Wornat, Mary J.
    Hung, Francisco R.
    Herckes, Pierre R.
    Valsaraj, Kalliat T.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [2] Chemistry and Photochemistry of Pyruvic Acid at the Air-Water Interface
    Kappes, Keaten J.
    Deal, Alexandra M.
    Jespersen, Malte F.
    Blair, Sandra L.
    Doussin, Jean-Francois
    Cazaunau, Mathieu
    Pangui, Edouard
    Hopper, Brianna N.
    Johnson, Matthew S.
    Vaida, Veronica
    JOURNAL OF PHYSICAL CHEMISTRY A, 2021, 125 (04): : 1036 - 1049
  • [3] Controlling the morphology and slippage of the air-water interface on superhydrophobic surfaces
    Zhang, Mengzhuo
    Hu, Haibao
    Wen, Jun
    Ren, Liuzhen
    Xie, Luo
    EXPERIMENTS IN FLUIDS, 2023, 64 (06)
  • [4] Sphingomyelin at the air-water interface
    Vaknin, D
    Kelley, MS
    Ocko, BM
    JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (16): : 7697 - 7704
  • [5] ON INSTABILITY OF AN AIR-WATER INTERFACE
    GANGADHA.T
    RAO, NSL
    SEETHARA.K
    INDIAN JOURNAL OF TECHNOLOGY, 1970, 8 (04): : 120 - &
  • [6] Methylglyoxal at the air-water interface
    Wren, Sumi N.
    McWilliams, Laura E.
    Valley, Nicholas A.
    Richmond, Geraldine L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [7] ON THE INSTABILITY OF AN AIR-WATER INTERFACE
    GANGADHARAIAH T
    LAKSHMANA RAO NS
    KSEETHARAMIAH
    1970, 8 (04): : 120 - 124
  • [8] Assembly of amphiphilic phenylacetylene macrocycles at the air-water interface and on solid surfaces
    Shetty, AS
    Fischer, PR
    Stork, KF
    Bohn, PW
    Moore, JS
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (39) : 9409 - 9414
  • [9] Investigation of adsorption of surfactant at the air-water, interface with quantum chemistry method
    Chen MeiLing
    Wang ZhengWu
    Wang HaiJun
    Zhang GeXin
    Tao FuMing
    CHINESE SCIENCE BULLETIN, 2007, 52 (11): : 1451 - 1455
  • [10] GENERAL AND PHYSICAL CHEMISTRY .6. MONOLAYERS AT AIR-WATER INTERFACE
    MINGINS, J
    STANDISH, MM
    ANNUAL REPORTS OF THE PROGRESS OF CHEMISTRY, 1966, 63 : 91 - &