'Super-reduced' iron under physiologically-relevant conditions

被引:12
作者
Mot, Augustin [1 ]
Zoltan, Kis [1 ]
Svistunenko, Dimitri A. [2 ]
Damian, Grigore [1 ]
Silaghi-Dumitrescu, Radu [1 ,3 ]
Makarov, Sergei V. [1 ,3 ]
机构
[1] Univ Babes Bolyai, RO-400028 Cluj Napoca, Romania
[2] Univ Essex, Dept Biol Sci, Colchester CO4 3SQ, Essex, England
[3] State Univ Chem & Technol, Ivanovo 153000, Russia
基金
俄罗斯基础研究基金会;
关键词
PHTHALOCYANINE CATALYZED REDUCTION; AQUEOUS-SOLUTION; COBALT; DITHIONITE; MECHANISM; KINETICS; NITRITE; CO2;
D O I
10.1039/b919517c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
EPR spectroscopy is employed to demonstrate chemical production of formally Fe(I) and Fe(0) states of phthalocyanines in water at room temperature, and physiologically-relevant pH.
引用
收藏
页码:1464 / 1466
页数:3
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