Potential theory of the depletion interaction in the colloid-polymer mixtures

被引:20
作者
Chervanyov, A. I. [1 ]
Heinrich, G. [1 ]
机构
[1] Leibniz Inst Polymer Res Dresden, D-01069 Dresden, Germany
关键词
colloids; many-body problems; polymer structure; proteins; SMALL MESOSCOPIC PARTICLES; PROTEIN; THERMODYNAMICS; SPHERES;
D O I
10.1063/1.3273416
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
By developing and making use of the potential theory of the polymer-mediated interaction between spherical colloids, we investigate the many-body effects on the depletion interaction among these colloids in the colloid-polymer mixture. As our main results, we obtain analytic expressions for the polymer end density in the presence of the colloids and the many-body depletion potential acting between these colloids in the "protein" limit. We present a comparison of our theoretical findings with the results of recent computer simulations.
引用
收藏
页数:7
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