Hydrogen storage in water-stable metal-organic frameworks incorporating 1,3-and 1,4-benzenedipyrazolate

被引:180
作者
Choi, Hye Jin [1 ]
Dinca, Mircea [1 ]
Dailly, Anne [2 ]
Long, Jeffrey R. [1 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Gen Motors Corp, Chem & Environm Sci Lab, Warren, MI 48090 USA
关键词
ZEOLITIC IMIDAZOLATE FRAMEWORKS; SINGLE-CRYSTAL TRANSFORMATIONS; ADSORPTION PROPERTIES; H-2; ADSORPTION; SORPTION; SPILLOVER; STRATEGY; BINDING; DESIGN; SITES;
D O I
10.1039/b917512a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pyrazolate-bridged metal-organic frameworks incorporating tetrahedral Zn2+ ions are shown to exhibit a high chemical stability in boiling water, organic solvents, and acidic media, and are assessed for their hydrogen storage properties.
引用
收藏
页码:117 / 123
页数:7
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