Effects of Sm Co-doping on Luminescent Properties of Sr4Al14O25:M (M=Mn4+, Cr3+) Phosphors

被引:7
|
作者
Xu, Yu-dong [1 ]
Peng, Xu-dong [1 ]
Wang, Lei [1 ]
Shi, Min [1 ]
Zhang, Yuan [1 ]
Wang, Quan [1 ]
Ding, Ning [2 ]
机构
[1] Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Peoples R China
[2] Bengbu Yucheng New Mat Sci & Technol Ltd Co, Bengbu 233000, Peoples R China
基金
中国国家自然科学基金;
关键词
Phosphor; Co-doping; Strontium aluminates; Energy transfer; ENERGY-TRANSFER; RED PHOSPHOR; WHITE LEDS; IONS; GREEN; MN; EU;
D O I
10.1063/1674-0068/28/cjcp1504071
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The Sr4Al14O25:M and doped Sr4Al14O25:M+Sm3+ (M=Mn4+, Cr3+) phosphors were synthesized by a solid-state reaction method and their luminescent properties were investigated. The results showed that the co-doping of Sm ions did not change the positions of excitation band and emission band but significantly improved the luminescent properties of Sr4Al14O25:Cr3+ phosphors; whereas, the emission intensity of Sr4Al14O25:Mn4+ was reduced remarkably when Sm ions were co-doped. In add-Lion, a radiative-form energy transfer from Sm3+ to Cr3+ was observed for the first time in the Cr, Sm co-doped Sr4Al14O25 phosphors. The results indicated that Sm ions could significantly improve the emission intensity of Sr4Al14O25:Cr3+, making the Sm(3+)co-doped Sr4Al14O25:Cr3+ phosphor a promising candidate for the applications in display and solid state lightening.
引用
收藏
页码:771 / 776
页数:6
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