Ceric ammonium nitrate (CAN) as oxidizing or nitrating reagent for organic reactions in ionic liquids

被引：28

作者：

Deleersnyder, Karen ^{[1
]}

Schaltin, Stijn ^{[2
]}

Fransaer, Jan ^{[2
]}

Binnemans, Koen ^{[1
]}

Parac-Vogt, Tatjana N. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, B-3001 Heverlee, Belgium

[2] Katholieke Univ Leuven, Dept MTM, B-3001 Heverlee, Belgium

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 32期

关键词：

SELECTIVE OXIDATION; SULFURIC-ACID; CERIUM(IV); HYDROQUINONES; DERIVATIVES; SILICA;

D O I：

10.1016/j.tetlet.2009.05.093

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of ceric ammonium nitrate, (NH4)(2)[Ce(NO3)(6)] or CAN, with naphthalene and 2-methylnaphthalene in the ionic liquid 1-ethyl-3-methylimidazolium triflate showed that the reaction products are strongly dependent on the water content of the ionic liquid and that cerium(IV) in the ionic liquid can electrochemically be regenerated. (C) 2009 Published by Elsevier Ltd.

引用

页码：4582 / 4586

页数：5

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