Trimetallic complexes containing 1,1′-Rc′(CC)2 units [Rc′ = ruthenocene-1,1′-diyl, Ru(η-C5H4-)2]

被引：14

作者：

Bruce, Michael I. ^{[1
]}

Jevric, Martyn

Perkins, Gary J.

Skelton, Brian W.

White, Allan H.

机构：

[1] Univ Adelaide, Sch Chem & Phys, Adelaide, SA 5005, Australia

[2] Univ Western Australia, SBBCS, Nedlands, WA 6009, Australia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 08期

关键词：

ethynyl complexes; ruthenocene; ruthenium-phosphine; X-ray structure; tcne cycloaddition;

D O I：

10.1016/j.jorganchem.2006.11.037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions between 1,1'-(Me3SiC equivalent to C)(2)Rc' [Rc' = ruthenocen-1, 1'-diyl, Ru(eta-C5H4-)(2)] and RuCl(PP)Cp' in the presence of KF gave 1,1'-{Cp(PP)RuC equivalent to C}(2)Rc' [Cp' = CP, PP = PPh3 1, P(m-tol)(3) 2, dppe 3, dppf 4; Cp' = Cp*, PP = dppe 5]. Compounds 1 and 2 react with tcne to give two diastereomers a/b of the allylic (vinylcarbene) complexes 6 and 7, while methylation of 5 gave the bis-vinylidene [1,1'-{Cp*(dppe)Ru=C=CMe}2Rc'](BPh4)(2) (8). The X-ray structures of 4, 6b and 8 have been determined. Cyclic voltammograms indicate that there is some electronic communication between the ruthenium end-groups through the Rc' centre. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：1757 / 1765

页数：9

共 28 条

[1] CYCLOPENTADIENYLRUTHENIUM COMPLEXES WITH SULFUR DONOR LIGANDS .2. A COMPARATIVE-STUDY OF THE REACTIVITY OF RU(ETA-RC5H4)CL(L)2(R=H,CH3,CH3CO-L=CO,PH2PCH2CH2PPH2/2,P(CH2CH2CN)3) TOWARDS ANIONIC (S-S) DONOR LIGANDS [J].

ALONSO, AG ;

REVENTOS, LB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 338 (02) :249-254

[2]

Bruce M. I., 2004, ADV ORGANOMET CHEM, V50, P231

[3] Syntheses, structures, some reactions, and electrochemical oxidation of ferrocenylethynyl complexes of iron, ruthenium, and osmium [J].

Bruce, MI ;

Low, PJ ;

Hartl, F ;

Humphrey, PA ;

de Montigny, F ;

Jevric, M ;

Lapinte, C ;

Perkins, GJ ;

Roberts, RL ;

Skelton, BW ;

White, AH .

ORGANOMETALLICS, 2005, 24 (22) :5241-5255

[4] Syntheses, structures, and spectro-electrochemistry of {Cp*(PP)Ru}CCCC{Ru(PP)Cp*} (PP = dppm, dppe) and their mono- and dicationst [J].

Bruce, MI ;

Ellis, BG ;

Low, PJ ;

Skelton, BW ;

White, AH .

ORGANOMETALLICS, 2003, 22 (16) :3184-3198

[5] Syntheses and some reactions of complexes containing carbon chains capped by ferrocenyl and W(CO)3CP groups [J].

Bruce, MI ;

Smith, ME ;

Skelton, BW ;

White, AH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 637 :484-499

[6] An efficient synthesis of polyynyl and polyynediyl complexes of ruthenium(II) [J].

Bruce, MI ;

Hall, BC ;

Kelly, BD ;

Low, PJ ;

Skelton, BW ;

White, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (21) :3719-3728

[7] Oxidation chemistry of metal-bonded C4 chains:: A combined chemical, spectroelectrochemical, and computational study [J].

Bruce, MI ;

Low, PJ ;

Costuas, K ;

Halet, JF ;

Best, SP ;

Heath, GA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (09) :1949-1962

[8] Syntheses and reactions of ruthenium complexes containing C6 and C8 chains [J].

Bruce, MI ;

Kelly, BD ;

Skelton, BW ;

White, AH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 604 (02) :150-156

[9]

BRUCE MI, 1990, INORG SYNTH, V28, P20

[10] Synthetic, structural, electrochemical and electronic characterisation of heterobimetallic bis(acetylide) ferrocene complexes [J].

Colbert, MCB ;

Lewis, J ;

Long, NJ ;

Raithby, PR ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (01) :99-104

← 1 2 3 →