Synthesis, characterization and luminescent property of a novel zinc(II) 1,2,3,4-tetra(4-pyridyl)thiophene metal-organic framework

被引：14
作者：
Qiu, Ling [1 ]
Lin, Jianguo [1 ]
Xu, Yanyan [2 ]
机构：
[1] Jiangsu Inst Nucl Med, Minist Hlth, Key Lab Nucl Med, Wuxi 214063, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Zinc(II) complex; Crystal structure; Metal-organic framework; Luminescence; ACID N-OXIDE; COORDINATION POLYMERS; MOLECULES; DESIGN; LIGAND; HELIX;
D O I：
10.1016/j.inoche.2009.07.027
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel metal-organic framework (MOF) [Zn(TPT)(MPDCO)(H2O)center dot H2O](n) (TPT = 1,2,3,4-tetra (4-pyridyl)thiophene, MPDCO = 6-methylpyridine-2,4-dicarboxylic acid N-oxide) (1) was obtained via hydrothermal synthesis and characterized by the elemental analysis, IR spectroscopy, TG analysis, luminescent spectroscopy and single-crystal X-ray diffraction analysis. Single-crystal structural analysis reveals that a one-dimensional (1-D) ladderlike MOF is constructed through the mixed ligands, and it is further connected by the intermolecular hydrogen bonds to form a 3-D supramolecular network. Complex I exhibits efficient blue luminescence at room temperature, and the framework is stable below 235 degrees C. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：986 / 989
页数：4
相关论文
共 21 条
[1]   Cation-Triggered Drug Release from a Porous Zinc-Adeninate Metal-Organic Framework [J].
An, Jihyun ;
Geib, Steven J. ;
Rosi, Nathaniel L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (24) :8376-+
[2]   Polyfunctional inorganic-organic hybrid materials: An unusual kind of NLO active layered mixed metal oxalates with tunable magnetic properties and very large second harmonic generation [J].
Cariati, Elena ;
Macchi, Roberto ;
Roberto, Dominique ;
Ugo, Renato ;
Galli, Simona ;
Casati, Nicola ;
Macchi, Piero ;
Sironi, Angelo ;
Bogani, Lapo ;
Caneschi, Andrea ;
Gatteschi, Dante .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (30) :9410-9420
[3]   Multi-functional rare-earth hybrid layered networks: photoluminescence and catalysis studies [J].
Cunha-Silva, Luis ;
Lima, Sergio ;
Ananias, Duarte ;
Silva, Patricia ;
Mafra, Luis ;
Carlos, Luis D. ;
Pillinger, Martyn ;
Valente, Anabela A. ;
Almeida Paz, Filipe A. ;
Rocha, Joao .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (17) :2618-2632
[4]   A design strategy for four-connected coordination frameworks [J].
Dolomanov, OV ;
Cordes, DB ;
Champness, NR ;
Blake, AJ ;
Hanton, LR ;
Jameson, GB ;
Schröder, M ;
Wilson, C .
CHEMICAL COMMUNICATIONS, 2004, (06) :642-643
[5]   Crystallized frameworks with giant pores:: Are there limits to the possible? [J].
Férey, G ;
Mellot-Draznieks, C ;
Serre, C ;
Millange, F .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225
[6]   Rare earth coordination polymers with zeolite topology constructed from 4-connected building units [J].
Guo, Xiaodan ;
Zhu, Guangshan ;
Li, Zhongyue ;
Chen, Yan ;
Li, Xiaotian ;
Qiu, Shilun .
INORGANIC CHEMISTRY, 2006, 45 (10) :4065-4070
[7]   Crystalline-state guest-exchange and gas-adsorption phenomenon for a "Soft" supramolecular porous framework stacking by a rigid linear coordination polymer [J].
Hu, Sheng ;
He, Kun-Huan ;
Zeng, Ming-Hua ;
Zou, Hua-Hong ;
Jiang, Yi-Min .
INORGANIC CHEMISTRY, 2008, 47 (12) :5218-5224
[8]   Dynamic porous properties of coordination polymers inspired by hydrogen bonds [J].
Kitagawa, S ;
Uemura, K .
CHEMICAL SOCIETY REVIEWS, 2005, 34 (02) :109-119
[9]   Remarkably stable porous assembly of nanorods derived from a simple metal-organic framework [J].
Kumar, D. Krishna ;
Das, Amitava ;
Dastidar, Parthasarathi .
CRYSTAL GROWTH & DESIGN, 2007, 7 (02) :205-207
[10]   A POWDER TECHNIQUE FOR EVALUATION OF NONLINEAR OPTICAL MATERIALS [J].
KURTZ, SK ;
PERRY, TT .
IEEE JOURNAL OF QUANTUM ELECTRONICS, 1968, QE 4 (05) :333-+
123