Synthesis, characterization and luminescent property of a novel zinc(II) 1,2,3,4-tetra(4-pyridyl)thiophene metal-organic framework

被引：14

作者：

Qiu, Ling ^{[1
]}

Lin, Jianguo ^{[1
]}

Xu, Yanyan ^{[2
]}

机构：

[1] Jiangsu Inst Nucl Med, Minist Hlth, Key Lab Nucl Med, Wuxi 214063, Peoples R China

[2] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Zinc(II) complex; Crystal structure; Metal-organic framework; Luminescence; ACID N-OXIDE; COORDINATION POLYMERS; MOLECULES; DESIGN; LIGAND; HELIX;

D O I：

10.1016/j.inoche.2009.07.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel metal-organic framework (MOF) [Zn(TPT)(MPDCO)(H2O)center dot H2O](n) (TPT = 1,2,3,4-tetra (4-pyridyl)thiophene, MPDCO = 6-methylpyridine-2,4-dicarboxylic acid N-oxide) (1) was obtained via hydrothermal synthesis and characterized by the elemental analysis, IR spectroscopy, TG analysis, luminescent spectroscopy and single-crystal X-ray diffraction analysis. Single-crystal structural analysis reveals that a one-dimensional (1-D) ladderlike MOF is constructed through the mixed ligands, and it is further connected by the intermolecular hydrogen bonds to form a 3-D supramolecular network. Complex I exhibits efficient blue luminescence at room temperature, and the framework is stable below 235 degrees C. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：986 / 989

页数：4

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