Catalytic synthesis of polynorbornene and polynorbornadiene of low polydispersity index by [Ru(η5-C9H7)Cl(COD)] (COD=1,5-cyclooctadiene)

被引：16

作者：

Alvarez, P ^{[1
]}

Gimeno, J ^{[1
]}

Lastra, E ^{[1
]}

机构：

[1] Univ Oviedo, Dept Quim Organ & Inorgan, Fac Quim,CSIC, Inst Quim Organometal Enrique Moles,Unidad Asocia, E-33006 Oviedo, Spain

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 25期

关键词：

D O I：

10.1021/om020426h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermal ROMP of norbonene and norbornaSurnmar diene can be achieved at room temperature and stereoselectively using as initiator the indenyl complex [RU(q'd5C9LH7)C1(COD)1. The polymers are obtained in high yields showing a low polydispersity index, in the range 1. 1 4.7, and high M, and Mu, values in a monomodal distribution. Catalytic polymerization of norbornadiene also takes place in the presence of air. A mechanism for the formation of the active carbene species via deprotonation of the cyclooctadiene ligand is proposed.

引用

页码：5678 / 5680

页数：3

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