Flacourside, a new 4-oxo-2-cyclopentenylmethyl glucoside from the fruit juice of Flacourtia indica

被引：15

作者：

Amarasinghe, Nilupa R.

Jayasinghe, Lalith

Hara, Noriyuki

Fujimoto, Yoshinori

机构：

[1] Inst Fundamental Studies, Nat Prod Project, Kandy, Sri Lanka

[2] Tokyo Inst Technol, Dept Chem & Mat Sci, Tokyo 1528551, Japan

来源：

FOOD CHEMISTRY | 2007年 / 102卷 / 01期

关键词：

Flacourtia indica; flacourside; flacourtiaceae; 4-oxo-2-cyclopentenylmethanol;

D O I：

10.1016/j.foodchem.2006.05.004

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new glucoside ester, named flacourside, has been isolated together with known methyl 6-O-(E)-p-coumaroyl glucopyranoside and 6-O-(E)-p-coumaroyl glucopyranose from the n-butanol extract of fruit juice of the Flacourtia indica. The structure of flacourside has been determined to be 4-oxo-2-cyclopentenylmethyl 6-O-(E)-p-coumaroyl-beta-D-glucopyranoside on the basis of spectroscopic studies. (c) 2006 Elsevier Ltd. All rights reserved.

引用

收藏

页码：95 / 97

页数：3

相关论文

共 14 条

[1]

Ashton MS., 1997, A field guide to the common trees and shrubs of Sri Lanka

[2] (-)FLACOURTIN, A PHENOLIC GLUCOSIDE ESTER FROM FLACOURTIA-INDICA [J].

BHAUMIK, PK ;

GUHA, KP ;

BISWAS, GK ;

MUKHERJEE, B .

PHYTOCHEMISTRY, 1987, 26 (11) :3090-3091

[3] Intramolecular, nucleophile-catalyzed aldol-lactonization (NCAL) reactions:: Catalytic, asymmetric synthesis of bicyclic β-lactones [J].

Cortez, GS ;

Tennyson, RL ;

Romo, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (32) :7945-7946

[4] On the isolation of sitosterin-(6′-O-acyl)-β-D-glucopyranosides from Flacourtia indica and on unexpected formation of gels by the triacetate [J].

Dehmlow, EV ;

Guntenhöner, M ;

van Ree, T .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2000, 55 (3-4) :333-335

[5]

FRANCOIS MT, 1961, CR HEBD ACAD SCI, V252, P315

[6] Phenolic glycosides of forage legume Onobrychis viciifolia [J].

Lu, YR ;

Sun, Y ;

Foo, LY ;

McNabb, WC ;

Molan, AL .

PHYTOCHEMISTRY, 2000, 55 (01) :67-75

[7] THE SYNTHESIS AND STEREOCHEMISTRY OF CHAULMOOGRIC ACID [J].

MISLOW, K ;

STEINBERG, IV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (14) :3807-3810

[8] OCCURRENCE AND BIOSYNTHESIS OF CYCLOPENTENYL FATTY-ACIDS IN LEAVES AND CHLOROPLASTS OF FLACOURTIACEAE [J].

REHFELDT, AG ;

SCHULTE, E ;

SPENER, F .

PHYTOCHEMISTRY, 1980, 19 (08) :1685-1689

[9] Fast repair of deoxynucleotide radical cations by phenylpropanoid glycosides (PPGs) and their analogs [J].

Shi, YM ;

Kang, JH ;

Lin, WZ ;

Fan, PT ;

Jia, ZJ ;

Yao, SD ;

Wang, WF ;

Zheng, RL .

BIOCHIMICA ET BIOPHYSICA ACTA-GENERAL SUBJECTS, 1999, 1472 (1-2) :279-289

[10] PHENYLPROPANOID GLUCOSE ESTERS FROM PRUNUS-BUERGERIANA [J].

SHIMOMURA, H ;

SASHIDA, Y ;

ADACHI, T .

PHYTOCHEMISTRY, 1988, 27 (02) :641-644