Synthesis, vibrational spectrum and structure of the tetracyanoborate K[B(CN)4]•CH3CN

被引：15

作者：

Kueppers, Torsten

Koeckerling, Martin

Willner, Helge

机构：

[1] Univ Rostock, Inst Chem Anorgan Festkorperchem, D-18051 Rostock, Germany

[2] Berg Univ Wuppertal, FC C Anorgan Chem, D-42119 Wuppertal, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 02期

关键词：

tetracyanoborate; potassium; vibrational spectroscopy; crystal structure; acetonitrile adduct;

D O I：

10.1002/zaac.200600277

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new tetracyanoborate K[B(CN)(4)](CH3CN)-C-. was synthesized by dissolution of the solvent-free K[B(CN)(4)] in acetonitrile and subsequent careful crystallization. The crystal structure has been determined by single-crystal X-ray diffraction. It crystallizes in the orthorhombic space group P2(1)2(1)2(1) with Z = 4. Some comparisons with related structures are made, and the vibrational spectrum is discussed.

引用

页码：280 / 284

页数：5

共 34 条

[1]

[Anonymous], 2003, SADABS SOFTWARE CCD

[2]

[Anonymous], CHEMTRACTS INORG CHE

[3]

[Anonymous], [No title captured]

[4]

Berkei M, 2002, Z ANORG ALLG CHEM, V628, P1734, DOI 10.1002/1521-3749(200208)628:8<1734::AID-ZAAC1734>3.0.CO

[5]

2-Q

[6] An efficient synthesis for tetracyanoborates by sinter processes [J].

Bernhardt, E ;

Finze, M ;

Willner, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (7-8) :1229-1234

[7] The reactions of M[BF4] (M= Li, K) and(C2H5)2O•BF3 with (CH3)3SiCN.: Formation of M[BFx(CN)4-x] (M= Li, K; x=1, 2) and (CH3)3SiNCBFx(CN)3-,,9-x, (x=0, 1) [J].

Bernhardt, E ;

Berkei, M ;

Willner, H ;

Schürmann, M .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (04) :677-685

[8]

Bernhardt E, 2000, Z ANORG ALLG CHEM, V626, P560, DOI 10.1002/(SICI)1521-3749(200002)626:2<560::AID-ZAAC560>3.0.CO

[9]

2-E

[10]

Bernhardt E, 2001, CHEM-EUR J, V7, P4696, DOI 10.1002/1521-3765(20011105)7:21<4696::AID-CHEM4696>3.0.CO

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