Synthesis of Vinyl Sulfones through Visible Light-Induced Decarboxylative Sulfonylation of Cinnamic Acids with Disulfides

被引：16
|
作者：
Li, Xuezhi [1 ]
Wang, Min [1 ]
Wang, Zhihui [1 ]
Wang, Lei [1 ,2 ]
机构：
[1] Huaibei Normal Univ, Dept Chem, Huaibei 235000, Anhui, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 8卷 / 08期
基金：
中国国家自然科学基金;
关键词：
vinyl sulfones; visible-light-induced synthesis; decarboxylative sulfonylation; cinnamic acids; disulfides; ENANTIOSELECTIVE 1,3-DIPOLAR CYCLOADDITION; IODINE-MEDIATED SYNTHESIS; SELECTIVE SYNTHESIS; C-S; CATALYZED SYNTHESIS; (E)-VINYL SULFONES; AZOMETHINE YLIDES; MOLECULAR-OXYGEN; BOND FORMATION; SULFONYLHYDRAZIDES;
D O I：
10.1002/ajoc.201900386
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Visible light-induced decarboxylative sulfonylation of cinnamic acids with disulfides for the synthesis of vinyl sulfones was developed. The reaction underwent smoothly in the presence of Ru(Phen)(3)(PF6)(2) as a photocatalyst, Cs2CO3 as a base in DMSO at room temperature under blue LED (450-455 nm) irradiation and air atmosphere, generating the desired products in good yields. It provides an alternative route to vinyl sulfones with disulfides as sulfonylation reagent in the advantages of mild conditions, simple system and wide functional group tolerance.
引用
收藏
页码：1426 / 1435
页数：10
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