Synthesis and structure of N-salicylidene-o-aminophenolato gallium(III) complexes

被引：21

作者：

Kagkelari, Adamantia ^{[1
]}

Papaefstathiou, Giannis S. ^{[2
]}

Raptopoulou, Catherine P. ^{[3
]}

Zafiropoulos, Theodoros F. ^{[1
]}

机构：

[1] Univ Patras, Dept Chem, Patras 26504, Greece

[2] Univ Athens, Inorgan Chem Lab, Dept Chem, Panepistimiopolis 15771, Zografou, Greece

[3] NCSR Demokritos, Inst Mat Sci, Aghia Paraskevi 15310, Greece

来源：

POLYHEDRON | 2009年 / 28卷 / 15期

关键词：

Crystal structure; Gallium(III) complexes; IR spectra; Mononuclear six-coordinated Ga(III) complexes; N-salicylidene-o-aminophenol; LIGHT-EMITTING DEVICES; CRYSTAL-STRUCTURE; METAL; ELECTROLUMINESCENCE; CHEMISTRY; LIGAND; ACID;

D O I：

10.1016/j.poly.2009.04.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of Ga(acac)(3) with N-salicylidene-o-aminophenol (saphH(2)) and its 5-methyl (5MesaphH(2)) and 5-bromo (5BrsaphH(2)) derivatives in alcohols afforded the complexes [Ga(acac)(saph)(EtOH)] (1), [Ga(acac)(5Mesaph)(MeOH)] (2) and [Ga(acac)(5Brsaph)(EtOH)] (3), respectively, in good yields. The crystal structures of 1 and 2 have been solved by single-crystal X-ray crystallography. All three complexes are mononuclear with the Ga-III atoms being surrounded by a dianionic tridentate Schiff base ligand, one bidentate acac(-) ligand and a terminal alcohol molecule. Characteristic IR data are discussed in terms of the nature of bonding and the structures of the three complexes. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：3279 / 3283

页数：5

共 25 条

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Barron A.R., 1994, ENCY INORGANIC CHEM, V3, P1249

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