Crystal structure, bioactivities, and electrochemistry properties of four diverse complexes with a new pyrazole ligand

被引：14

作者：

Hu, Feilong ^{[1
]}

Yin, Xianhong ^{[1
]}

Lu, Jie ^{[2
]}

Mi, Yan ^{[1
]}

Zhuang, Jichang ^{[1
]}

Luo, Weiqiang ^{[1
]}

机构：

[1] Guangxi Univ Nationalities, Coll Chem & Ecol Engn, Nanning, Peoples R China

[2] Guangxi Univ, Coll Life Sci & Technol, Nanning 530004, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 63卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Pyrazole; Electrochemistry; Crystal structure; Supramolecular; MAGNETIC-PROPERTIES; COORDINATION POLYMERS; METAL-COMPLEXES; WATER; ACID; LUMINESCENCE; MONONUCLEAR; NETWORKS; CLUSTER; COPPER;

D O I：

10.1080/00958970903373930

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four complexes, [Cu(cmpa)(Hpdbl)]center dot 2H(2)O (1), [Cd(cmpa)(2)]center dot 2.5H(2)O (2), [Cu(cmpa)(2)]center dot 2.5H(2)O (3), and [Pb(cmpa) 2]center dot 2.5H(2)O (4), have been synthesized and characterized based on the pyrazole ligand (Hcmpa = 3-chloro-6-(3,5-dimethy-1-yl)picolinic acid, H(2)pdbl = pyridine-2,6-dicarboxylic acid). Complexes 1-4 showed 3-D supramolecular architectures that are connected through hydrogen bonds and aromatic pi-pi interactions. Preliminary antibacterial activities of the complexes indicated selective inhibition for the tested strains. The electrochemistry of 1-4 was studied by cyclic voltammetry in DMSO using a glassy carbon working electrode.

引用

页码：263 / 272

页数：10

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