Room-Temperature Rechargeable Ca-Ion Based Hybrid Batteries with High Rate Capability and Long-Term Cycling Life

被引：56
作者：
Lang, Jihui [1 ,2 ]
Jiang, Chunlei [1 ,2 ]
Fang, Yue [1 ,2 ]
Shi, Lei [2 ]
Miao, Shijie [2 ]
Tang, Yongbing [1 ,2 ]
机构：
[1] Jilin Normal Univ, Minist Educ, Key Lab Funct Mat Phys & Chem, Siping 136000, Peoples R China
[2] Chinese Acad Sci, Shenzhen Inst Adv Technol, Funct Thin Films Res Ctr, Shenzhen 518055, Peoples R China
来源：
ADVANCED ENERGY MATERIALS | 2019年 / 9卷 / 29期
基金：
中国国家自然科学基金;
关键词：
batteries; calcium; energy storage; room-temperature; CALCIUM; INTERCALATION; ENERGY; PERFORMANCE; ELECTRODE; BEHAVIOR; HOST;
D O I：
10.1002/aenm.201901099
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Calcium-ion batteries (CIBs) are promising energy storage devices due to the merits of natural abundance, similar standard reduction potential to lithium, and bivalent-ion characteristic of calcium. However, the development of CIBs is hindered by the low rate capability and poor cycling performance at room temperature. Here, a highly reversible room-temperature calcium-ion based hybrid battery is realized by a tri-ion strategy, which significantly improves the diffusion kinetics of calcium ions. The optimized CIB shows high rate capability of 15 C as well as excellent cycling stability over 1500 cycles with 86% capacity retention at 5 C, at room temperature, which is the best result of reported calcium-ion based full batteries.
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页数：6
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共 69 条
[1]   Trends in Aluminium-Based Intercalation Batteries [J].
Ambroz, Filip ;
Macdonald, Thomas J. ;
Nann, Thomas .
ADVANCED ENERGY MATERIALS, 2017, 7 (15)
[2]   A Joint Computational and Experimental Evaluation of CaMn2O4 Polymorphs as Cathode Materials for Ca Ion Batteries [J].
Arroyo-de Dompablo, M. Elena ;
Krich, Christopher ;
Nava-Avendano, Jessica ;
Biskup, Neven ;
Rosa Palacin, M. ;
Barde, Fanny .
CHEMISTRY OF MATERIALS, 2016, 28 (19) :6886-6893
[3]   THE ELECTROCHEMICAL-BEHAVIOR OF CALCIUM ELECTRODES IN A FEW ORGANIC ELECTROLYTES [J].
AURBACH, D ;
SKALETSKY, R ;
GOFER, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (12) :3536-3545
[4]   Hybrid-ion - A lithium-ion cell based on a sodium insertion material [J].
Barker, J ;
Gover, RKB ;
Burns, P ;
Bryan, AJ .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (04) :A190-A192
[5]   Vanadium oxide-propylene carbonate composite as a host for the intercalation of polyvalent cations [J].
Bervas, M ;
Klein, LC ;
Amatucci, GG .
SOLID STATE IONICS, 2005, 176 (37-38) :2735-2747
[6]   Advancing towards a veritable calcium-ion battery: CaCo2O4 positive electrode material [J].
Cabello, Marta ;
Nacimiento, Francisco ;
Gonzalez, Jose R. ;
Ortiz, Gregorio ;
Alcantara, Ricardo ;
Lavela, Pedro ;
Perez-Vicente, Carlos ;
Tirado, Jose L. .
ELECTROCHEMISTRY COMMUNICATIONS, 2016, 67 :59-64
[7]   Alkaline-Acid Zn-H2O Fuel Cell for the Simultaneous Generation of Hydrogen and Electricity [J].
Cai, Pingwei ;
Li, Yan ;
Wang, Genxiang ;
Wen, Zhenhai .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (15) :3910-+
[8]   Sodium-Ion Battery Materials and Electrochemical Properties Reviewed [J].
Chayambuka, Kudakwashe ;
Mulder, Grietus ;
Danilov, Dmitri L. ;
Notten, Peter H. L. .
ADVANCED ENERGY MATERIALS, 2018, 8 (16)
[9]   Rechargeable Mg-Li hybrid batteries: status and challenges [J].
Cheng, Yingwen ;
Chang, Hee Jung ;
Dong, Hui ;
Choi, Daiwon ;
Sprenkle, Vincent L. ;
Liu, Jun ;
Yao, Yan ;
Li, Guosheng .
JOURNAL OF MATERIALS RESEARCH, 2016, 31 (20) :3125-3141
[10]   Sodium-Ion Batteries: From Academic Research to Practical Commercialization [J].
Deng, Jianqiu ;
Luo, Wen-Bin ;
Chou, Shu-Lei ;
Liu, Hua-Kun ;
Dou, Shi-Xue .
ADVANCED ENERGY MATERIALS, 2018, 8 (04)
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