Applications of MXene (Ti3C2Tx) in photocatalysis: a review

被引:138
|
作者
Li, Xing [1 ]
Bai, Yang [1 ]
Shi, Xian [2 ]
Su, Na [1 ]
Nie, Gongzhe [1 ]
Zhang, Rumeng [3 ]
Nie, Hongbo [1 ,4 ]
Ye, Liqun [1 ,5 ]
机构
[1] Southwest Petr Univ, Sch Oil & Nat Gas Engn, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Peoples R China
[2] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Chengdu 610054, Peoples R China
[3] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Key Lab Ecol Secur Water Source Reg Midline Proje, Nanyang 473061, Peoples R China
[4] CNOOC China Co LTD, Tianjing Branch, Tianjin 300452, Peoples R China
[5] China Three Gorges Univ, Coll Mat & Chem Engn, Key Lab Inorgan Nonmet Crystalline & Energy Conve, Yichang 443002, Peoples R China
来源
MATERIALS ADVANCES | 2021年 / 2卷 / 05期
基金
中国国家自然科学基金;
关键词
TRANSITION-METAL CARBIDES; HYDROGEN-PRODUCTION; CO2; REDUCTION; ENVIRONMENTAL APPLICATIONS; SURFACE FUNCTIONALIZATION; 2-DIMENSIONAL TI3C2; ENERGY-CONVERSION; SCHOTTKY-JUNCTION; GRAPHITIC CARBON; 001; FACETS;
D O I
10.1039/d0ma00938e
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
MXenes are two-dimensional nanomaterials, which can be constructed from different elements. The rich interlayer groups, surface groups, and the flexible layer spacing of MXenes make them ideal catalysts. Among these, Ti3C2Tx has gained particular attention as a photocatalyst for photocatalytic CO2 reduction reactions (CO2RR), hydrogen evolution reactions (HER), and photocatalytic degradation reactions. The structure of Ti3C2Tx, hydrophilic surface functional groups, and the Gibbs free energy for hydrogen adsorption lead to the excellent photocatalytic HER performance of this material. Numerous surface defects on Ti3C2Tx also provide plentiful CO2 adsorption sites for CO2RR. It is the structure of two-dimensional nanomaterials and their high-speed electron transport channels that enable their excellent catalytic oxidation activity. However, at present, there are still challenges that limit their further application, the most significant of which is the material stability. In order to overcome this, the synthetic routes to prepare these photocatalysts need to be adapted.
引用
收藏
页码:1570 / 1594
页数:25
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