Polystyrene-block-poly(2-cinnamoylethyl methacrylate) tadpole molecules

被引：56

作者：

Tao, J ^{[1
]}

Liu, GJ ^{[1
]}

机构：

[1] UNIV CALGARY,DEPT CHEM,CALGARY,AB T2N 1N4,CANADA

来源：

MACROMOLECULES | 1997年 / 30卷 / 08期

关键词：

D O I：

10.1021/ma961422p

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In THF/cyclopentane (CP) or THF/cyclohexane (CH) mixtures with sufficiently high CP or CH contents, polystyrene-block-poly(2-cinnamoylethyl metharylate) (PS-b-PCEMA) forms micelles with PCEMA as the core. Coexisting with the micelles are unimer chains. The unimers are expected to have the tadpole conformation with the PS block assuming the normal random-coil conformation and the PCEMA block clustering together like a globule. Photo-cross-linking the PCEMA globule of the unimers enabled our first preparation of permanent tadpole molecules from diblock copolymers. The tadpole conformation has been confirmed by our GPC, light scattering, and NMR study.

引用

页码：2408 / 2411

页数：4

共 16 条

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