Silicon nanoparticles-graphene paper composites for Li ion battery anodes

被引:726
作者
Lee, Jeong K. [2 ]
Smith, Kurt B. [1 ]
Hayner, Cary M. [1 ]
Kung, Harold H. [1 ]
机构
[1] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA
[2] Dong A Univ, Dept Chem Engn, Pusan 604714, South Korea
基金
美国国家科学基金会;
关键词
LITHIUM SECONDARY BATTERIES; ELECTROCHEMICAL PROPERTIES; GRAPHITE OXIDE; PERFORMANCE; ELECTRODES; CARBON; REDUCTION; CAPACITY;
D O I
10.1039/b919738a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Composites of Si nanoparticles highly dispersed between graphene sheets, and supported by a 3-D network of graphite formed by reconstituting regions of graphene stacks exhibit high Li ion storage capacities and cycling stability. An electrode was prepared with a storage capacity > 2200 mA h g(-1) after 50 cycles and > 1500 mA h g(-1) after 200 cycles that decreased by < 0.5% per cycle.
引用
收藏
页码:2025 / 2027
页数:3
相关论文
共 20 条
[1]   Honeycomb Carbon: A Review of Graphene [J].
Allen, Matthew J. ;
Tung, Vincent C. ;
Kaner, Richard B. .
CHEMICAL REVIEWS, 2010, 110 (01) :132-145
[2]   Structural and electrochemical properties of fullerene-coated silicon thin film as anode materials for lithium secondary batteries [J].
Arie, Arenst Andreas ;
Song, Jin O. ;
Lee, Joong Kee .
MATERIALS CHEMISTRY AND PHYSICS, 2009, 113 (01) :249-254
[3]   ALL-SOLID LITHIUM ELECTRODES WITH MIXED-CONDUCTOR MATRIX [J].
BOUKAMP, BA ;
LESH, GC ;
HUGGINS, RA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (04) :725-729
[4]   High-performance lithium battery anodes using silicon nanowires [J].
Chan, Candace K. ;
Peng, Hailin ;
Liu, Gao ;
McIlwrath, Kevin ;
Zhang, Xiao Feng ;
Huggins, Robert A. ;
Cui, Yi .
NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35
[5]   Preparation and characterization of graphene oxide paper [J].
Dikin, Dmitriy A. ;
Stankovich, Sasha ;
Zimney, Eric J. ;
Piner, Richard D. ;
Dommett, Geoffrey H. B. ;
Evmenenko, Guennadi ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2007, 448 (7152) :457-460
[6]  
Gao B, 2001, ADV MATER, V13, P816, DOI 10.1002/1521-4095(200106)13:11<816::AID-ADMA816>3.0.CO
[7]  
2-P
[8]   Superior storage performance of a Si@SiOx/C nanocomposite as anode material for lithium-ion batteries [J].
Hu, Yong-Sheng ;
Demir-Cakan, Rezan ;
Titirici, Maria-Magdalena ;
Mueller, Jens-Oliver ;
Schloegl, Robert ;
Antonietti, Markus ;
Maier, Joachim .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (09) :1645-1649
[9]   Three-Dimensional Porous Silicon Particles for Use in High-Performance Lithium Secondary Batteries [J].
Kim, Hyunjung ;
Han, Byunghee ;
Choo, Jaebum ;
Cho, Jaephil .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (52) :10151-10154
[10]   Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations [J].
Kovtyukhova, NI ;
Ollivier, PJ ;
Martin, BR ;
Mallouk, TE ;
Chizhik, SA ;
Buzaneva, EV ;
Gorchinskiy, AD .
CHEMISTRY OF MATERIALS, 1999, 11 (03) :771-778