Simultaneous Adsorption/Oxidation of NO and SO2 over Al-Cu Composite Metal Oxides Supported on MCM-41 at Low Temperature

被引：6
作者：
Li, Shan [1 ]
Li, Kai [1 ]
Hao, Jiming [1 ,2 ]
Ning, Ping [1 ]
Tang, Lihong [1 ]
Wang, Chi [1 ]
机构：
[1] Kunming Univ Sci & Technol, Fac Environm Sci & Engn, Kunming 650500, Peoples R China
[2] Tsinghua Univ, Sch Environm, Beijing 100084, Peoples R China
来源：
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN | 2017年 / 50卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Al-Cu/MCM-41; Adsorbent; Simultaneous Adsorption/Oxidation; NO and SO2; Preparation Conditions; Low Temperature; SELECTIVE CATALYTIC-REDUCTION; MESOPOROUS SILICA; NITRIC-OXIDE; COPPER; CU-AL-MCM-41; PERFORMANCE; MECHANISM; OXIDATION; AMMONIA; EXHAUST;
D O I：
10.1252/jcej.15we131
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Al-Cu composite metal oxides were supported on MCM-41 to simultaneous adsorption/oxidation of NO and SO2 from Coal-fired flue gas in this work. The material was prepared by hydrothermal synthesis method and the synthetic conditions such as aluminum content, the second metal selection, the second metal content and calcination temperature were investigated. The experiment results showed that the adsorption/oxidation effect achieved the best when the ratio was Si: 02 Al: 0.02 Cu at 90 degrees C. The synthesized materials were characterized by N-2 adsorption-desorption measurements, transmission electron microscope (TEM) and energy dispersive spectrometer (EDS). Compared with other adsorbents, Al-Cu-MCM-41 had larger specific surface area and total pore volume by N-2 adsorption-desorption measurements. Meanwhile, the additions of aluminum and copper did not change mesoporous structure of MCM-41 and the active components could be dispersed uniformly within the framework of Al-Cu-MCM-41 by TEM. In addition, the results of EDS explained that the presence of active components was convinced and sulfur element was detected on inactivated Al-Cu-MCM-41adsorbent. The analysis results illustrated that the presence of aluminum and copper could enhance the adsorption/oxidation capacity of NO and SO2. Therefore, it could infer that chemical adsorption probably had a better removal effect than physical adsorption.
引用
收藏
页码：376 / 382
页数：7
相关论文
共 50 条
[11]   Effect of SO2 Treatment at High Temperature on Soot Oxidation Activity of Cu-Ce-Al Mixed Oxides [J].
Wu, Xiaodong ;
Lin, Fan ;
Weng, Duan ;
Jia, Liwei ;
Shen, Meiqing .
CATALYSIS LETTERS, 2009, 131 (3-4) :463-468
[12]   Effect of calcination temperature on desulfurization performance over Mn x O y supported on MCM-41 at low temperatures [J].
Zhang, Jiaojing ;
Wang, Guojian ;
Wang, Wenyi ;
Song, Hua ;
Li, Fengsheng .
RESEARCH ON CHEMICAL INTERMEDIATES, 2016, 42 (06) :6003-6012
[13]   A comparative study of Zr, Al or Sr doped Mn/MCM-41 for NH3-SCR and resistance to SO2/H2O [J].
Li, Jing ;
He, Shulin ;
Guo, Jiaxiu ;
Liang, Juan ;
Chu, Yinghao ;
Li, Jianjun .
NEW JOURNAL OF CHEMISTRY, 2022, 46 (42) :20456-20472
[14]   One pot microwave synthesis of MCM-41/Cu based MOF composite with improved CO2 adsorption and selectivity [J].
Tari, Nesa Esmaeilian ;
Tadjarodi, Azadeh ;
Tamnanloo, Javad ;
Fatemi, Shohreh .
MICROPOROUS AND MESOPOROUS MATERIALS, 2016, 231 :154-162
[15]   Photothermal catalytic CO2 oxidative dehydrogenation of propane over Co-Mn bimetallic oxides supported on MCM-41 molecular sieve [J].
Zhu, Zhan-Jun ;
He, Zhen-Hong ;
Wang, Sen-Wang ;
Wu, Bao-Ting ;
Tian, Yue ;
Sun, Yong-Chang ;
Wang, Kuan ;
Wang, Weitao ;
Wang, Huan ;
Liu, Zhao-Tie .
MOLECULAR CATALYSIS, 2024, 559
[16]   Highly dispersed CuyAlOx, mixed oxides as superior low-temperature alkali metal and SO2 resistant NH3-SCR catalysts [J].
Yan, Qinghua ;
Nie, Yu ;
Yang, Ruoyan ;
Cui, Yuhan ;
O'Hare, Dermot ;
Wang, Qiang .
APPLIED CATALYSIS A-GENERAL, 2017, 538 :37-50
[17]   Sonosynthesis of VOx/MCM-41 nanocatalyst enhanced by various metal oxides (Mg, AL, Zr) for CO2-oxidative dehydrogenation of ethane to ethylene [J].
Taghavinezhad, Parisa ;
Haghighi, Mohanimad ;
Alizadeh, Reza .
MICROPOROUS AND MESOPOROUS MATERIALS, 2018, 261 :63-78
[18]   Efficient and selective hydrogenation of quinolines over FeNiCu/MCM-41 catalyst at low temperature: Synergism of Fe-Ni and Ni-Cu alloys [J].
Wang, Kuan ;
Cao, Zhe ;
Wang, Junlei ;
He, Zhen-Hong ;
Wang, Dan ;
Zhang, Rong-Rong ;
Wang, Weitao ;
Yang, Yang ;
Liu, Zhao-Tie .
MOLECULAR CATALYSIS, 2022, 520
[19]   Hydrocracking of Low-Temperature Coal Tar over CoMo Catalysts Supported on ZrO2-Al2O3 Composite Oxides [J].
Jiake, Yang ;
Meng Jipeng ;
Zuo Tongjiu ;
Lu Jiangyin .
CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY, 2020, 22 (01) :24-31
[20]   Simultaneous removal of NOX and SO2 with H2O2 over Fe based catalysts at low temperature [J].
Ding, Jie ;
Zhong, Qin ;
Zhang, Shule .
RSC ADVANCES, 2014, 4 (11) :5394-5398
12345