Vibrations of the S-S bond in elemental sulfur and organic polysulfides: a structural guide

被引：108

作者：

Trofimov, Boris A. ^{[1
]}

Sinegovskaya, Lidiya M. ^{[1
]}

Gusarova, Nina K. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia

来源：

JOURNAL OF SULFUR CHEMISTRY | 2009年 / 30卷 / 05期

关键词：

Raman and infrared spectra; elemental sulfur; disulfides; polysulfides; NORMAL-COORDINATE TREATMENT; VALENCE FORCE FIELD; LIQUID-PHASE RAMAN; DIALKYL DISULFIDES; MOLECULAR-CONFORMATIONS; INFRARED-SPECTRA; CYCLO-UNDECASULFUR; DIALLYL DISULFIDE; CRYSTAL-STRUCTURE; CONSTANTS;

D O I：

10.1080/17415990902998579

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review summarizes and analyzes in comparative manner the S-S bond vibrations in IR and Raman spectra of elemental sulfur and organosulfur compounds containing disulfide and polysulfide moieties. It is intentionally biased toward application of the experimental S-S bond frequencies for structural elucidation of sulfur compounds. It was shown that the S-S bond frequencies are a useful tool for identification of the elemental sulfur modifications, organic disufides and polysulfides. Particular attention is paid to the correlation between the S-S bond frequencies and the molecular structure.

引用

页码：518 / 554

页数：37

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