Nitrous oxide decomposition active site on Ni-MgO catalysts characterized by X-ray absorption fine structure spectroscopy

被引：12

作者：

Izumi, Y ^{[1
]}

Shimizu, T ^{[1
]}

Kobayashi, T ^{[1
]}

Aika, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Environm Chem & Engn, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 12期

关键词：

D O I：

10.1039/b002773l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A contracted Ni2+ coordination site distorted in the direction of Ni ... Mg and Ni ... Ni was found to be responsible for catalytic N2O decomposition when Ni2+ is diluted in a MgO matrix (Ni2+/Mg2+ atomic ratio approximate to 1.0) based on a local structure study by nickel K-edge X-ray absorption fine structure spectroscopy.

引用

页码：1053 / 1054

页数：2

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