Stimuli-Responsive Reversible Assembly of 2D and 3D Metallosupramolecular Architectures

被引：85

作者：

Lusby, Paul J. ^{[1
]}

Mueller, Peter ^{[1
]}

Pike, Sarah J. ^{[1
]}

Slawin, Alexandra M. Z. ^{[2
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 45期

基金：

英国工程与自然科学研究理事会;

关键词：

LIGAND; PRISMS; GUEST; HOST; CAGE;

D O I：

10.1021/ja907297z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The discovery of interconvertible platinum coordination modes, which reveals and masks cis coordinating groups upon addition of acid and base, respectively, has been exploited to facilitate stimuli-responsive assembly and disassembly of both two- and three-dimensional metallosupramolecular architectures. Treatment of a binclear platinum complex with acid along with ditopic and tritopic donor ligands generated a molecular square and a trigonal prism, respectively, in good to high yield. These complexes were unambiguously identified using electrospray mass spectrometry, H-1 NMR spectroscopy, and X-ray crystallography. Both assemblies can be disassembled into their constituent parts simply by treatment with base, and the prism can be cycled between the assembled and disassembled states by the alternate addition of acid and base.

引用

页码：16398 / +

页数：6

共 27 条

[1]

BALBOIU M, 2004, CHEM-EUR J, V10, P2953

[2] Design and formation of a large tetrahedral cluster using 1,1′-binaphthyl ligands [J].

Biros, Shannon M. ;

Yeh, Robert M. ;

Raymond, Kenneth N. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (32) :6062-6064

[3] Halide-induced supramolecular ligand rearrangement [J].

Brown, AM ;

Ovchinnikov, MV ;

Stern, CL ;

Mirkin, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (44) :14316-14317

[4] Coordination-driven face-directed self-assembly of trigonal prisms. Face-based conformational chirality [J].

Caskey, Douglas C. ;

Yamamoto, Takuya ;

Addicott, Chris ;

Shoemaker, Richard K. ;

Vacek, Jaroslav ;

Hawkridge, Adam M. ;

Muddiman, David C. ;

Kottas, Gregg S. ;

Michl, Josef ;

Stang, Peter J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (24) :7620-7628

[5] C-H activation induced by water.: Monocyclometalated to dicyclometalated:: C∧N∧C tridentate platinum complexes [J].

Cave, GWV ;

Fanizzi, FP ;

Deeth, RJ ;

Errington, W ;

Rourke, JP .

ORGANOMETALLICS, 2000, 19 (07) :1355-1364

[6] Supramolecular recognition forces: An examination of weak metal-metal interactions in host-guest formation [J].

Crowley, JD ;

Steele, IM ;

Bosnich, B .

INORGANIC CHEMISTRY, 2005, 44 (09) :2989-2991

[7] Coordination assemblies from a Pd(II)-cornered square complex [J].

Fujita, M ;

Tominaga, M ;

Hori, A ;

Therrien, B .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :369-378

[8] PREPARATION OF A MACROCYCLIC POLYNUCLEAR COMPLEX, [(EN)PD(4,4'-BPY)]4(NO3)8, WHICH RECOGNIZES AN ORGANIC-MOLECULE IN AQUEOUS-MEDIA [J].

FUJITA, M ;

YAZAKI, J ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5645-5647

[9] 3 nm-scale molecular switching between fluorescent coordination capsule and nonfluorescent cage [J].

Harano, Koji ;

Hiraoka, Shuichi ;

Shionoya, Mitsuhiko .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (17) :5300-+

[10] Triangular and tetrahedral array of silver(I) ions by a novel disk-shaped tridentate ligand: Dynamic control of coordination equilibrium of the silver(I) complexes [J].

Hiraoka, S ;

Yi, T ;

Shiro, M ;

Shionoya, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (49) :14510-14511

← 1 2 3 →