Epoxysilane rearrangement: Mechanistic studies and synthetic applications

被引：6

作者：

Sasaki, Michiko ^{[1
]}

Takeda, Kei ^{[1
]}

机构：

[1] Hiroshima Univ, Grad Sch Med Sci, Dept Synth Organ Chem, Minami Ku, Hiroshima 7348553, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2006年 / 64卷 / 11期

关键词：

D O I：

10.5059/yukigoseikyokaishi.64.1148

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mechanistic studies on and synthetic application of epoxysilane rearrangement, a novel synthetic use of alpha,beta-epoxysilanes, in which an anion-induced ring-opening of epoxide and Brook rearrangement in the resulting alpha-silyl alkoxide occur in a tandem fashion to provide a beta-siloxy allyl anion, are described.

引用

页码：1148 / 1158

页数：11

共 86 条

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