Vapor-liquid equilibrium data at 343 K and excess molar enthalpy data at 298 K for the binary systems of ethanol plus 2,4,4-trimethyl-1-pentene and 2-propanol plus 2,4,4-trimethyl-1-pentene

被引:25
作者
Pokki, JP
Rehák, K
Kim, Y
Matous, J
Aittamaa, J
机构
[1] Helsinki Univ Technol, Dept Chem Technol, FIN-02015 Helsinki, Finland
[2] Inst Chem Technol, Dept Chem Phys, Prague 16628 6, Czech Republic
关键词
D O I
10.1021/je025556b
中图分类号
O414.1 [热力学];
学科分类号
摘要
Isothermal vapor-liquid equilibrium data were measured for two binary systems, ethanol + 2,4,4-trimethyl-1-pentene and 2-propanol + 2,4,4-trimethyl-1-pentene, at 343 K. The measurements were made with a circulation still. The composition of liquid and condensed vapor phase was determined with a gas chromatograph. Excess molar enthalpy data were measured for the same binary systems at 298 K. Both systems indicate positive deviations from Raoult's law and exhibit azeotropic behavior.
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页码:75 / 80
页数:6
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