Red-blood-cell-like BSA/Zn3(PO4)2 hybrid particles: Preparation and application to adsorption of heavy metal ions

被引：63

作者：

Zhang, Baoliang ^{[1
]}

Li, Peitao ^{[1
]}

Zhang, Hepeng ^{[1
]}

Li, Xiangjie ^{[1
]}

Tian, Lei ^{[1
]}

Wang, Hai ^{[1
]}

Chen, Xin ^{[1
]}

Ali, Nisar ^{[1
]}

Ali, Zafar ^{[1
]}

Zhang, Qiuyu ^{[1
]}

机构：

[1] Northwestern Polytech Univ, Sch Sci, Dept Appl Chem, Minist Educ,Key Lab Appl Phys & Chem Space, Xian 710072, Peoples R China

来源：

APPLIED SURFACE SCIENCE | 2016年 / 366卷

关键词：

Hybrid particle; BSA; Zn-3(PO4)(2); Adsorption; Heavy metal ions; FACILE SYNTHESIS; NANOFLOWERS; MICROSPHERES; NANOPARTICLES; PERFORMANCE;

D O I：

10.1016/j.apsusc.2016.01.074

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel kind of red-blood-cell-like bovine serum albumin (BSA)/Zn-3(PO4)(2) hybrid particle is prepared at room temperature by a facile and rapid one-step method based on coordination between BSA and zinc ion. The morphology of the monodisperse hybrid particle shows oblate spheroidal type with a one sided single hole on the surface. The hybrid particle is constructed with BSA/Zn-3(PO4)(2) nanoplates of 35 nm thick. The average particle size of hybrid particle is 2.3 mu m, and its BET specific surface area is 146.64 cm(2)/g. To clarify the evolution of BSA/Zn-3(PO4)(2) hybrid particle, SEM and elemental analysis as a function of particle growth time are investigated. The formation mechanism of BSA/Zn-3(PO4)(2) hybrid particle, which can be described as crystallization, coordination and self-assembly process, is illustrated in detail. The as-prepared BSA/Zn-3(PO4)(2) hybrid particle is used for adsorption of Cu2'. The hybrid particle displayed excellent adsorption properties on Cu2+. The adsorption efficiency of BSA/Zn-3(PO4)(2) hybrid particles at 5 min and 30min are 86.33% and 98.9%, respectively. The maximum adsorption capacity is 6.85 mg/g. Thus, this kind of novel adsorbent shows potential application value in ultra-fast and highly efficient removal of Cu2+. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：328 / 338

页数：11

共 25 条

[1] Protein-inorganic hybrid nanoflowers as ultrasensitive electrochemical cytosensing Interfaces for evaluation of cell surface sialic acid [J].