Reactivity and characteristics of Pd/MOF and Pd/calcinated-MOF catalysts for CO oxidation reaction: Effect of oxygen and hydrogen

被引：15

作者：

Abbasi, Fateme ^{[1
]}

Karimi-Sabet, Javad ^{[2
]}

Ghotbi, Cyrus ^{[1
]}

机构：

[1] Sharif Univ Technol, Dept Petr & Chem Engn, Tehran, Iran

[2] Nucl Sci & Technol Res Inst NSTRI Tehran, Nucl Fuel Res Sch, Tehran, Iran

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2021年 / 46卷 / 24期

关键词：

MIL-101(Cr); HKUST-1; NH2-MIL-101(Cr); Hydrogen; Calcination; CO oxidation;

D O I：

10.1016/j.ijhydene.2021.01.237

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For the first time, the effect of calcination process on characteristics and catalytic performances of Pd supported on different MOFs (MIL-101(Cr), NH2-MIL-101(Cr), and HKUST-1) was evaluated. Besides, the various orders of calcination process and reduction one on Pd/MOF and Pd/calcinated-MOF were studied, and their performances in CO oxidation reaction were presented to find the effect of H-2 and O-2. Results showed that the effect of calcination and reduction processes on the catalytic activities and characteristics strongly depends on the nature of MOF. Among MIL-based catalysts, the catalyst with no calcination treatment showed the best activity. Among MNH2-based catalysts, high activity was obtained for Pd/MNH2, Pd/MNH2-C, and Pd/MNH2(RC) samples and Pd/calcinated-MNH2 was the best. Catalytic activities of HKUST-1-based catalysts decreased with calcination due to high changes in their structures. The results are useful for predicting the performance of MOFs in oxidation processes, especially reactions in which high oxygen concentrations are involved. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：12822 / 12834

页数：13

共 74 条

[1] An advanced composite with ultrafast photocatalytic performance for the degradation of antibiotics by natural sunlight without oxidizing the source over TMU-5@Ni-Ti LDH: mechanistic insight and toxicity assessment [J].