Versatile phosphors BaY2Si3O10:RE (RE = Ce3+, Tb3+, Eu3+) for light-emitting diodes

被引:72
作者
Liu, Wei-Ren [1 ]
Lin, Chun Che [2 ]
Chiu, Yi-Chen [1 ]
Yeh, Yao-Tsung [1 ]
Jang, Shyue-Ming [1 ]
Liu, Ru-Shi [2 ]
Cheng, Bing-Ming [3 ]
机构
[1] ITRI, Mat & Chem Res Labs, Hsinchu 300, Taiwan
[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
[3] Natl Synchrotron Radiat Res Ctr, Hsinchu 300, Taiwan
关键词
LUMINESCENCE PROPERTIES; PHOTOLUMINESCENCE; EARTH; EU2+;
D O I
10.1364/OE.17.018103
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Rare-earth-activated BaY2Si3O10 (BYSO) phosphors were synthesized via a solid-state reaction. BaY2Si3O10:Ce3+ yields an indigo-blue emission peak at 404 nm according to excitation at 334 nm attributed to the Ce3+ 4f -> 5d transition. BaY2Si3O10:Tb3+ typically generates green emission peaks resulting from the D-5(4)-> F-7(J) transition. BaY2Si3O10:Eu3+ exhibits red emission peaks upon excitation at 393 nm. The quantum efficiency of these phosphors was found to be 53%, 55%, and 63% of commodity. The results in this work demonstrate that these phosphors with new compositions are good candidate luminescent materials for use in plasma display panels and light-emitting diodes, excited from VUV to UV. (C) 2009 Optical Society of America
引用
收藏
页码:18103 / 18109
页数:7
相关论文
共 20 条
[1]   Photoluminescence properties of a novel phosphor, Na3La9O3(BO3)8:RE3+ (RE = Eu,Tb) [J].
Bai, Xiaoyan ;
Zhang, Guochun ;
Fu, Peizhen .
JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (05) :1792-1795
[2]   TEMPERATURE-DEPENDENT STUDIES OF CATHODOLUMINESCENCE OF GREEN BAND OF ZNO CRYSTALS [J].
BHUSHAN, S ;
CHUKICHEV, MV .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1988, 7 (04) :319-321
[3]  
BLASSE G, 1969, PHILIPS RES REP, V24, P131
[4]  
Blasse G., 1994, LUMINESCENT MAT
[5]   Concentration quenching of Eu2+ in Ca2MgSi2O7:Eu2+ phosphor [J].
Jiang, L ;
Chang, CK ;
Mao, DL ;
Feng, CL .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2003, 103 (03) :271-275
[6]   BaY2Si3O10:: a new flux-grown trisilicate [J].
Kolitsch, Uwe ;
Wierbicka, Maria ;
Tillmanns, Ekkehart .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2006, 62 :I97-I99
[7]   Sr3Al10SiO20:Eu2+ as a blue luminescent material for plasma displays [J].
Kubota, S ;
Shimada, M .
APPLIED PHYSICS LETTERS, 2002, 81 (15) :2749-2751
[8]   Full-color and thermally stable KSrPO4:Ln (Ln = Eu, Tb, Sm) phosphors for white-light-emitting diodes [J].
Lin, C. C. ;
Liu, R. S. ;
Tang, Y. S. ;
Hu, S. F. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (09) :J248-J251
[9]   A new luminescent material:: Li2CaSiO4:Eu2+ [J].
Liu, Jie ;
Sun, Hayue ;
Shi, Chunshan .
MATERIALS LETTERS, 2006, 60 (23) :2830-2833
[10]   A study on the luminescence properties of CaAlBO4:RE3+ (RE=Ce, Tb, and Eu) phosphors [J].
Liu, Wei-Ren ;
Chiu, Yi-Chen ;
Tung, Chien-Yueh ;
Yeh, Yao-Tsung ;
Jang, Shyue-Ming ;
Chen, Teng-Ming .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (09) :J252-J255