Photocatalytic Oxidation of Alcohols on Pt/TiO2 and Nafion-Coated TiO2

被引：0

作者：

Guzman, Felipe ^{[1
]}

Yu, Zhiqiang ^{[1
]}

Chuang, Steven S. C. ^{[1
]}

机构：

[1] Univ Akron, Dept Chem & Biomol Engn, Akron, OH 44325 USA

来源：

CATALYSIS OF ORGANIC REACTIONS | 2009年 / 123卷

关键词：

FORMIC-ACID; ETHANOL; ACETONE; ETHOXY; WATER; FTIR;

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Photocatalytic oxidation of ethanol on Pt/TiO2 and Nafion coated TiO2 catalysts were studied using in situ infrared IR techniques. Infrared studies show that the reaction produced acetaldehyde, acetic acid, acetate, formic acid, formate, and CO2/H2O. Modification of the TiO2 catalyst by Pt and Nafion slowed down the oxidation reaction through site blocking. Incorporation of Pt was found to favor formation of formate (HCOO-), indicating Pt decreases the rate of oxidation of formate more than that of its formation.

引用

页码：463 / 472

页数：10

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