Synthesis, phase composition and structural and conductive properties of ferroelectric microparticles based on ATiOx (A = Ba, Ca, Sr)

被引:48
作者
Kozlovskiy, A. L. [1 ,2 ]
Kenzhina, I. E. [2 ,3 ]
Zdorovets, M., V [2 ,3 ,4 ]
Saiymova, M. [1 ]
Tishkevich, D., I [5 ]
Trukhanov, S., V [5 ]
Trukhanov, A., V [5 ]
机构
[1] Kazakh Russian Int Univ, Aktobe, Kazakhstan
[2] Inst Nucl Phys Republ Kazakhstan, Alma Ata, Kazakhstan
[3] LN Gumilyov Eurasian Natl Univ, Nur Sultan, Kazakhstan
[4] Ural Fed Univ, Ekaterinburg, Russia
[5] NAS Belarus, SSPA Sci & Pract Mat Res Ctr, Minsk 220072, BELARUS
关键词
Ferroelectrics; Barium titanate; Microparticles; Peroxide-like structures; DIELECTRIC-PROPERTIES; GRAIN-SIZE; BATIO3; CERAMICS; ELECTRICAL-PROPERTIES; TRANSFORMATIONS; BEHAVIOR; TRANSITION; PARTICLES;
D O I
10.1016/j.ceramint.2019.05.279
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The paper presents the results of a study of structural, optical and conductive properties of ferroelectric microparticles based on ATiO(x) (A = Ba, Ca, Sr) obtained by solid-phase synthesis. According to the data obtained, as a result of the synthesis microparticles of dendroid form were obtained. During the study, the dependences of the change in the phase composition and crystallographic characteristics on the choice of component A in the structure of a ferroelectric are established. Studies of conductive and optical characteristics of investigated microparticles were conducted. During tests of conductive characteristics of microparticles, the nonlinearity of the current - voltage characteristics was established due to the presence of impurity inclusions in the structure and a high concentration of vacancy and dislocation defects, which have a significant effect on the ballistic nature of charge transfer.
引用
收藏
页码:17236 / 17242
页数:7
相关论文
共 53 条
[21]   Dynamics of changes in structural properties of AlN ceramics after Xe+22 ion irradiation [J].
Kozlovskiy, A. ;
Dukenbayev, K. ;
Kenzhina, I. ;
Tosi, D. ;
Zdorovets, M. .
VACUUM, 2018, 155 :412-422
[22]   Investigation of the influence of irradiation with Fe+7 ions on structural properties of AlN ceramics [J].
Kozlovskiy, A. ;
Dukenbayev, K. ;
Ivanov, I. ;
Kozin, S. ;
Aleksandrenko, V. ;
Kurakhmedov, A. ;
Sambaev, E. ;
Kenzhina, I. ;
Tosi, D. ;
Loginov, V. ;
Zdorovets, M. .
MATERIALS RESEARCH EXPRESS, 2018, 5 (06)
[23]   Study of phase transformations, structural, corrosion properties and cytotoxicity of magnetite-based nanoparticles [J].
Kozlovskiy, A. L. ;
Ermekova, A. E. ;
Korolkov, I. V. ;
Chudoba, D. ;
Jazdzewska, M. ;
Ludzik, K. ;
Nazarova, A. ;
Marciniak, B. ;
Kontek, R. ;
Shumskaya, A. E. ;
Zdorovets, M. V. .
VACUUM, 2019, 163 :236-247
[24]  
Lee JK, 2001, J AM CERAM SOC, V84, P2001
[25]   Effects of Bi2O3 and Cr2Ti3O9 Co-doping on dielectric properties in BaTiO3-based ceramics [J].
Liu, Dan ;
Pu, Yongping ;
Shi, Xuan .
VACUUM, 2012, 86 (10) :1568-1571
[26]   Optical, electrical, and photoelectric properties of nitrogen-doped perovskite ferroelectric BaTiO3 ceramics [J].
Long, Peiqing ;
Chen, Chen ;
Pang, Dongfang ;
Liu, Xitao ;
Yi, Zhiguo .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2019, 102 (04) :1741-1747
[27]   Size effect on dielectric properties of fine-grained BaTiO3 ceramics [J].
Luan, WL ;
Gao, L ;
Guo, JK .
CERAMICS INTERNATIONAL, 1999, 25 (08) :727-729
[28]   SIMULTANEOUS STRUCTURE AND SIZE-STRAIN REFINEMENT BY THE RIETVELD METHOD [J].
LUTTEROTTI, L ;
SCARDI, P .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1990, 23 :246-252
[29]  
Min Zhang, 2018, CERAM INT, V44
[30]   EFFECT OF RARE-EARTH IONS ON ELECTRICAL CONDUCTIVITY OF BATIO3 CERAMICS [J].
MURAKAMI, T ;
MIYASHITA, T ;
NAKAHARA, M ;
SEKINE, E .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1973, 56 (06) :294-297