Synthesis, phase composition and structural and conductive properties of ferroelectric microparticles based on ATiOx (A = Ba, Ca, Sr)

被引:48
作者
Kozlovskiy, A. L. [1 ,2 ]
Kenzhina, I. E. [2 ,3 ]
Zdorovets, M., V [2 ,3 ,4 ]
Saiymova, M. [1 ]
Tishkevich, D., I [5 ]
Trukhanov, S., V [5 ]
Trukhanov, A., V [5 ]
机构
[1] Kazakh Russian Int Univ, Aktobe, Kazakhstan
[2] Inst Nucl Phys Republ Kazakhstan, Alma Ata, Kazakhstan
[3] LN Gumilyov Eurasian Natl Univ, Nur Sultan, Kazakhstan
[4] Ural Fed Univ, Ekaterinburg, Russia
[5] NAS Belarus, SSPA Sci & Pract Mat Res Ctr, Minsk 220072, BELARUS
关键词
Ferroelectrics; Barium titanate; Microparticles; Peroxide-like structures; DIELECTRIC-PROPERTIES; GRAIN-SIZE; BATIO3; CERAMICS; ELECTRICAL-PROPERTIES; TRANSFORMATIONS; BEHAVIOR; TRANSITION; PARTICLES;
D O I
10.1016/j.ceramint.2019.05.279
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The paper presents the results of a study of structural, optical and conductive properties of ferroelectric microparticles based on ATiO(x) (A = Ba, Ca, Sr) obtained by solid-phase synthesis. According to the data obtained, as a result of the synthesis microparticles of dendroid form were obtained. During the study, the dependences of the change in the phase composition and crystallographic characteristics on the choice of component A in the structure of a ferroelectric are established. Studies of conductive and optical characteristics of investigated microparticles were conducted. During tests of conductive characteristics of microparticles, the nonlinearity of the current - voltage characteristics was established due to the presence of impurity inclusions in the structure and a high concentration of vacancy and dislocation defects, which have a significant effect on the ballistic nature of charge transfer.
引用
收藏
页码:17236 / 17242
页数:7
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